Skip to main content
SpringerLink
Log in

Internal structure rebuilding reactions of crystalline and amorphous solids

  • Published:
Journal of thermal analysis Aims and scope Submit manuscript

Abstract

Structural mechanism of the internal thermal reactions of dehydration and dehydroxylation as of solids well as crystallization of their amorphous products and glasses are considered. They are multi-stage processes, realized through small translative displacements of polymerized anion network elements and diffusional shift of cations. It is the way to equilibrium state of the lowest energy consumption and the least energetic barrier to overcome.

Zusammenfassung

Es werden Strukturmechanismen von internen thermischen Reaktionen von Dehydratation und Dehydroxylierung sowie der Kristallisierung der entstehenden amorphen Reaktionsprodukte betrachtet. Dabei handelt es sich um mehrstufige Prozesse, die über kleine translative Verschiebungen von polimerisierten Elementen des Anionennetzwerkes und durch Diffusionsverschiebung von Kationen ablaufen. Dies ist der Weg zum Gleichgewichtszustand mit dem geringsten Energieverbrauch und der niedrigsten, zu überwindenden Energiebarriere.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. Pampuch, Bull. Grup. France Argiles, 23 (1971) 107.

    Google Scholar 

  2. S. Yariv and E. Mendelovici, Appl. Spect., 33 (1979) 410.

    Article  Google Scholar 

  3. H. R. Oswald, Thermochim. Acta, 135 (1988) 3.

    Article  Google Scholar 

  4. H. R. Oswald and A. Reller, J. Thermal Anal., 29 (1988) 67.

    Article  Google Scholar 

  5. L. Stoch, J. Thermal Anal., 29 (1984) 919.

    Google Scholar 

  6. L. Stoch, J. Thermal Anal., 32 (1987) 1651.

    Article  Google Scholar 

  7. L. Stoch, Thermochim. Acta, 110 (1987) 359.

    Article  Google Scholar 

  8. G. W. Brindley and J. Lamaitre, in Chemistry of Clays and Clay Minerals, A. C. D. Newman Ed., Mineralogical Soc. Monograph, London 1987, p. 319.

  9. I. Waclawska, L. Stoch, J. Paulik and F. Paulik, Thermochim. Acta, 133 (1988) 263.

    Article  Google Scholar 

  10. L. Stoch and I. Waclawska, J. Thermal Anal., 36 (1990) 2045.

    Article  Google Scholar 

  11. L. Stoch and I. Waclawska, Thermochim. Acta, (in press).

  12. R. Pampuch, M. Kawalska and W. Ptak, Pol. Acad. Sci. Kracow Div., Pr. Kom. Ceram., 17 (1971) 63.

    Google Scholar 

  13. L. Stoch, J. Thermal Anal., 37 (1991).

  14. L. Stoch, Thermochim. Acta, (in press).

  15. F. Koster van Gross, Proc. 9th Clay Conf., Strasbourg 1989, Sci. Geol. Mem., 89 (1990) 123.

    Google Scholar 

  16. H. Worzala, Z. Anorg. Allg. Chem., 445 (1987) 27.

    Article  Google Scholar 

  17. H. Nagata, S. Shimoda and T. Sudo, Clays and Clay Minerals, 22 (1974) 285.

    Google Scholar 

  18. Z. Strnad, Glass-Ceramics Materials, Elsevier, Amsterdam 1989.

    Google Scholar 

  19. L. Stoch, in Advanced Solid State Chemistry, Proc. 2nd Int. Symp. on Solid State Chem., Pardubice 1989, M. Frumar, V. Cerny and L. Tichy Eds., Elsevier, Amsterdam 1989, p. 298.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Academy of mining and metallurgy, 30-059, Cracow, Poland

    L. Stock

Authors
  1. L. Stock
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Stock, L. Internal structure rebuilding reactions of crystalline and amorphous solids. Journal of Thermal Analysis 38, 131–139 (1992). https://doi.org/10.1007/BF02109113

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02109113

Keywords

Search

Navigation