Abstract
An attribute of amorphous/glassy state is that it is a solid state in which the atoms or molecules are not arranged in any long-range regular order. A glass is traditionally understood as the product obtained from a melted material that has been cooled at a sufficiently high cooling rate to obtain a rigid material without crystallization. The term amorphous is more general and encompasses not only the glasses but also non-crystalline substances prepared by other routes such as precipitation from solution, etc. Most solid materials can be prepared in the glassy/amorphous state, so that many branches of science are touched with the problem of amorphous-state properties, such as glass science, polymer science, metallurgy, biology, pharmaceutical science, and many other scientific disciplines.
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References
Avrami M (1939) Kinetics of phase change. I. General theory. J Chem Phys 7:1103–1112
Avrami M (1940) Kinetics of phase change. II. Transformation-time relations for random distribution of nuclei. J Chem Phys 8:212–224
Avrami M (1941) Kinetics of phase change. III. Granulation, phase change, and microstructure kinetics of phase change. J Chem Phys 9:177–184
Kolmogorov AE (1937) On the statistic theory of metal crystallization (in Russian). Izv Akad Nauk SSSR Ser Mat 1:355–359
Johnson WA, Mehl RF (1939) Reaction kinetics in processes of nucleation and growth. Trans Am Inst Min Metall Pet Eng 135:416–458
Christian JW (1975) The theory of transformations in metals and alloys, 2nd edn. Pergamon Press, New York
Henderson DW (1979) Experimental analysis of non-isothermal transformations involving nucleation and growth. J Therm Anal 15:325–331
Henderson DW (1979) Thermal analysis of nonisothermal crystallization kinetics in glass forming liquids. J Non-Cryst Solids 30:301–315
Shepilov MP, Baik DS (1994) Computer simulation of crystallization kinetics for the model with simultaneous nucleation of randomly-oriented ellipsoidal crystals. J Non-Cryst Solids 171:141–156
Šesták J (1984) Thermophysical properties of solids. Their measurements and theoretical analysis. Elsevier, Amsterdam
Málek J (2000) Kinetic analysis of crystallization processes in amorphous materials. Thermochim Acta 355:239–253
Zanotto ED (1992) Crystallization of liquids and glasses. Braz J Phys 22:77–84
Zanotto ED (1996) The applicability of the general theory of phase transformations to glass crystallization. Thermochim Acta 280(281):73–82
Weinberg MC (1996) Glass-formation and crystallization kinetics. Thermochim Acta 280(281):63–71
Šesták J, Berggren G (1971) Study of kinetics of mechanism of solid state reactions at increasing temperature. Thermochim Acta 3:1–12
Šimon P (2011) Forty years of the Šesták–Berggren equation. Thermochim Acta 520:156–157
Brown ME, Dollimore D, Galwey AK (1980) Comprehensive chemical kinetics, vol 22. Elsevier, Amsterdam
Šimon P (2004) Isoconversional methods – fundamentals, meaning and application. J Therm Anal Calorim 76:123–132
Vyazovkin S (2007) Isoconversional kinetics, chapter 13. In: Brown M, Gallagher P (eds) Handbook of thermal analysis and calorimetry, vol 5. Elsevier, Amsterdam. ISBN 13:978-0-444-53123-0
Michaelsen C, Dahms C (1996) On the determination of nucleation and growth kinetics by calorimetry. Thermochim Acta 288:9–27
Šimon P (2005) Considerations on the single-step kinetics approximation. J Therm Anal Calorim 82:651–657
Šimon P (2005) Single-step kinetics approximation employing non-Arrhenius temperature functions. J Therm Anal Calorim 79:703–708
Flynn JH, Wall LA (1966) A quick, direct method for the determination of activation energy from thermogravimetric data. Polym Lett 4:323–328
Ozawa T (1965) A new method of analyzing thermogravimetric data. Bull Chem Soc Jpn 38:1881–1886
Doyle CD (1962) Estimating isothermal life from thermogravimetric data. J Appl Polym Sci 6:639–642
Coats AW, Redfern JP (1964) Kinetic parameters from thermogravimetric data. Nature 201:68–69
Sbirrazzuoli N, Girault Y, Elégant L (1997) Simulations for evaluation of kinetic methods in differential scanning calorimetry. Part 3 – peak maximum evolution methods and isoconversional methods. Thermochim Acta 293:25–37
Vyazovkin S (1997) Evaluation of activation energy of thermally stimulated solid-state reactions under arbitrary variation of temperature. J Comput Chem 18:393–402
Šimon P, Nemčeková K, Jóna E, Plško A, Ondrušová D (2005) Thermal stability of glass evaluated by the induction period of crystallization. Thermochim Acta 428:11–14
Šimon P, Illeková E, Mojumdar SC (2006) Kinetics of crystallization of metallic glasses studied by non-isothermal and isothermal DSC. J Therm Anal Calorim 83:67–69
Šimon P, Jóna E, Pavlík V (2008) Thermal properties of oxide glasses. Part III. Thermal stability of Li2O · 2SiO2 · nMeO2 glasses (Me = Ti, Zr). J Therm Anal Calorim 94:421–425
Friedman HL (1963) Kinetics of thermal degradation of char-forming plastics from thermogravimetry. Application to a phenol plastic. J Polym Sci 6C:183–195
Vyazovkin S (2001) Modification of the integral isoconversional method to account for variation in the activation energy. J Comput Chem 22:178–183
Kissinger HE (1957) Reaction kinetics in differential thermal analysis. Anal Chem 29:1702–1706
Chen LC, Spaepen F (1991) Analysis of calorimetric measurements of grain growth. J Appl Phys 69:679–688
Matusita K, Sakka S (1979) Kinetic study of the crystallisation of glass by differential scanning calorimetry. Phys Chem Glasses 20:81–84
Vyazovkin S, Burnham AK, Criado JM, Pérez-Maqueda LA, Popescu C, Sbirrazzuoli N (2011) ICTAC Kinetics Committee recommendations for performing kinetic computations on thermal analysis data. Thermochim Acta 520:1–19
Ozawa T (1971) Kinetic analysis of derivative curves in thermal analysis. Polymer 12:150–158
Ozawa T (1984) Nonisothermal kinetics of crystal growth from preexisting nuclei. Bull Chem Soc Jpn 57:639–643
Thomas P, Šimon P (2005) A pseudoisothermal kinetic analysis of the recrystallisation of nickel sulphide measured by non-isothermal DSC. J Therm Anal Calorim 80:77–80
Ozawa T (2005) Kinetics of growth from pre-existing surface nuclei. J Therm Anal Calorim 82:687–690
Ray CS, Day DE (1996) Identifying internal and surface crystallization by differential thermal analysis for the glass-to-crystal transformations. Thermochim Acta 280(281):163–174
Turnbull D, Cohen MH (1960) In: Mackenzie JD (ed) Modern aspects of the vitreous state. Butterworth, London, pp 38–62
Matusita K, Komatsu T, Yokota R (1984) Kinetics of non-isothermal crystallization process and activation energy for crystal growth in amorphous materials. J Mater Sci 19:291–296
Šimon P (2006) Induction periods: theory and applications. J Therm Anal Calorim 84:263–270
Starink MJ, Zahra AM (1997) An analysis method for nucleation and growth controlled reactions at constant heating rates. Thermochim Acta 292:159–168
Augis JA, Bennett JE (1978) Calculation of the Avrami parameters for heterogeneous solid state reactions using a modification of the Kissinger method. J Therm Anal Calorim 13:283–292
Dobreva A, Stoyanov A, Gutzow I (1991) Analysis of differential scanning calorimetry data on the nonisothermal kinetics of crystallization in polymer melts. J Appl Polym Sci Appl Polym Symp 48:473–480
Angell CA, Stell RC, Sichina W (1982) Viscosity-temperature function for sorbitol from combined viscosity and differential scanning calorimetry studies. J Phys Chem 86:1540–1542
Lacey D, Nestor G, Richardson MJ (1994) Structural recovery in isotropic and smectic glasses. Thermochim Acta 238:99–111
Vyazovkin S, Sbirrazzuoli N, Dranca I (2004) Variation of the effective activation energy throughout the glass transition. Macromol Rapid Commun 25:1708–1713
Flynn JH (1997) The temperature integral: its use and abuse. Thermochim Acta 300:83–92
Vyazovkin S, Wight CA (1997) Kinetics in solids. Ann Rev Phys Chem 48:125–149
Vyazovkin S (2000) Kinetic concepts of thermally stimulated reactions in solids: a view from a historical perspective. Int Revs Phys Chem 19:45–60
Vyazovkin S, Sbirrazzuoli N (2004) Isoconversional approach to evaluating the Hoffman–Lauritzen Parameters (U* and K g) from the overall rates of nonisothermal crystallization. Macromol Rapid Commun 25:733–738
Šimon P (2007) The single-step approximation: attributes, strong and weak sides. J Therm Anal Calorim 88:709–715
Vyazovkin S (2003) Reply to “What is meant by the term ‘variable activation energy’ when applied in the kinetics analyses of solid state decompositions (crystolysis reactions)?”. Thermochim Acta 397:269–271
Ozawa T (2002) Comments on “The non-isothermal devitrification of glasses in the CaO 4GeO2–SrO–4GeO2 composition range” by Catauro M, Marotta, A ((2001) Thermochimica Acta 371:121–126). Thermochim Acta 386:99–100
Frade JR, Queiroz CM, Fernandez MH (2004) Re-examination of effects of nucleation temperature and time on glass crystallization. J Non-Cryst Solids 333:271–277
Koga N, Šesták J (1991) Kinetic compensation effect as a mathematical consequence of the exponential rate constant. Thermochim Acta 182:201–208
Hodge LM (1994) Enthalpy relaxation and recovery in amorphous materials. J Non-Cryst Solids 169:211–266
Šimon P, Hynek D, Malíková M, Cibulková Z (2008) Extrapolation of accelerated thermooxidative tests to lower temperatures applying non-Arrhenius temperature functions. J Therm Anal Calorim 93:817–821
Šimon P (2009) Material stability predictions applying a new non-Arrhenian temperature function. J Therm Anal Calorim 97:391–396
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Šimon, P., Thomas, P.S. (2012). Application of Isoconversional Methods for the Processes Occurring in Glassy and Amorphous Materials. In: Šesták, J., Šimon, P. (eds) Thermal analysis of Micro, Nano- and Non-Crystalline Materials. Hot Topics in Thermal Analysis and Calorimetry, vol 9. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3150-1_11
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