Skip to main content
Log in

Thermal decomposition kinetics of sodium bicarbonate by differential thermal analysis

  • Notes
  • Published:
Journal of thermal analysis Aims and scope Submit manuscript

Abstract

The thermal decomposition of sodium bicarbonate has been studied by DTA. It has been shown that the application of the first order kinetic equation provides a convenient quantitative description of the DTA curves. The influence of particle size, dilution, rate of heating and the size of the sample holder has been examined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. H. J. Borchardt andF. Daniels, J. Amer. Chem. Soc., 79 (1957) 41.

    Article  CAS  Google Scholar 

  2. H. E. Kissinger, Anal. Chem., 29 (1957) 1702; J. Research Natl. Bur. Standards, 57 (1956) 217.

    Article  CAS  Google Scholar 

  3. G. O. Piloyan, I. D. Ryabchikov andO. S. Novikova, Nature, 212 (1966) 1229.

    Article  CAS  Google Scholar 

  4. L. Reich, J. Inorg. Nucl. Chem., 28 (1966) 1329.

    Article  CAS  Google Scholar 

  5. I. Barshad, Amer. Mineral., 37 (1952) 667.

    CAS  Google Scholar 

  6. V. M. Padmanabhan, S. C. Saraiya andA. K. Sundaram, J. Inorg. Nucl. Chem., 12 (1960) 356.

    Article  CAS  Google Scholar 

  7. W. W. Wendlandt, J. Chem. Educ., 38 (1961) 571.

    Article  CAS  Google Scholar 

  8. J. M. Haschke andW. W. Wendlandt, Anal. Chim. Acta, 32 (1965) 386.

    Article  CAS  Google Scholar 

  9. R. L. Reed, L. Weber andB. S. Gottfried, Ind. Eng. Chem. Fundamentals, 4 (1965) 38.

    Article  CAS  Google Scholar 

  10. R. Melling, F. W. Wilburn andR. M. McIntosh, Anal. Chem., 41 (1969) 1275.

    Article  CAS  Google Scholar 

  11. A. R. Carthew, Amer. Mineral., 40 (1955) 107.

    CAS  Google Scholar 

  12. E. Martinez, ibid., 46 (1961) 901.

    CAS  Google Scholar 

  13. J. L. Kulp andA. F. Trites, ibid., 36 (1951) 23.

    CAS  Google Scholar 

  14. P. Bayliss, Nature, 201 (1964) 1019; 207 (1965) 284.

    Article  CAS  Google Scholar 

  15. H. E. Rose andJ. E. English, Nature, 216 (1967) 1045; Brit. Chem. Eng., 13 (1968) 1135

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

The authors wish to thank Shri G. V. U. Rao, Metallurgy Division, B.A.R.C., for the microscopic determination of the particle size of sodium bicarbonate samples.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Subramanian, K.S., Radhakrishnan, T.P. & Sundaram, A.K. Thermal decomposition kinetics of sodium bicarbonate by differential thermal analysis. Journal of Thermal Analysis 4, 89–93 (1972). https://doi.org/10.1007/BF02100954

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02100954

Keywords

Navigation