Abstract
The thermal decomposition of sodium bicarbonate has been studied by DTA. It has been shown that the application of the first order kinetic equation provides a convenient quantitative description of the DTA curves. The influence of particle size, dilution, rate of heating and the size of the sample holder has been examined.
Similar content being viewed by others
References
H. J. Borchardt andF. Daniels, J. Amer. Chem. Soc., 79 (1957) 41.
H. E. Kissinger, Anal. Chem., 29 (1957) 1702; J. Research Natl. Bur. Standards, 57 (1956) 217.
G. O. Piloyan, I. D. Ryabchikov andO. S. Novikova, Nature, 212 (1966) 1229.
L. Reich, J. Inorg. Nucl. Chem., 28 (1966) 1329.
I. Barshad, Amer. Mineral., 37 (1952) 667.
V. M. Padmanabhan, S. C. Saraiya andA. K. Sundaram, J. Inorg. Nucl. Chem., 12 (1960) 356.
W. W. Wendlandt, J. Chem. Educ., 38 (1961) 571.
J. M. Haschke andW. W. Wendlandt, Anal. Chim. Acta, 32 (1965) 386.
R. L. Reed, L. Weber andB. S. Gottfried, Ind. Eng. Chem. Fundamentals, 4 (1965) 38.
R. Melling, F. W. Wilburn andR. M. McIntosh, Anal. Chem., 41 (1969) 1275.
A. R. Carthew, Amer. Mineral., 40 (1955) 107.
E. Martinez, ibid., 46 (1961) 901.
J. L. Kulp andA. F. Trites, ibid., 36 (1951) 23.
P. Bayliss, Nature, 201 (1964) 1019; 207 (1965) 284.
H. E. Rose andJ. E. English, Nature, 216 (1967) 1045; Brit. Chem. Eng., 13 (1968) 1135
Author information
Authors and Affiliations
Additional information
The authors wish to thank Shri G. V. U. Rao, Metallurgy Division, B.A.R.C., for the microscopic determination of the particle size of sodium bicarbonate samples.
Rights and permissions
About this article
Cite this article
Subramanian, K.S., Radhakrishnan, T.P. & Sundaram, A.K. Thermal decomposition kinetics of sodium bicarbonate by differential thermal analysis. Journal of Thermal Analysis 4, 89–93 (1972). https://doi.org/10.1007/BF02100954
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF02100954