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Catalytic reactions of hydrocarbon with carbon dioxide over metallic catalysts

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Abstract

The catalytic reaction between hydrocarbons and carbon dioxide, e.g. CH4+ +CO2→2CO+2H2 and C6H6CH3+CO2→C6H6+2CO+H2, has been investigated over various metallic catalysts under atmospheric pressure. In general, Rh−Al2O3 catalyst was found to be excellent in activity and selectivity. The reaction rates were moderately dependent on the pressure of carbon dioxide, whereas it was little influenced by the pressure of hydrocarbon.

Abstract

Каталитическая реакция между углеводородом и двуокисью углерода, напр., CH4+CO2→2CO+2H2 или C6H5CH3+CO2→C6H6+2CO+X2, была исследована на различных катализаторах при атмосферном давлении. В общем, катализатор Rh−Al2O3 оказался превосходным по активности и селективности. Скорость реакции умеренно зависит от давления двуокиси углерода, в то время как слабо зависит от давления углеводорода.

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References

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Authors and Affiliations

  1. Department of Industrial Chemistry, Faculty of Engineering, Chiba University, 260, Chiba, Japan

    Y. Sakai, H. Saito, T. Sodesawa & F. Nozaki

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  1. Y. Sakai
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  2. H. Saito
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  3. T. Sodesawa
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  4. F. Nozaki
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Sakai, Y., Saito, H., Sodesawa, T. et al. Catalytic reactions of hydrocarbon with carbon dioxide over metallic catalysts. React Kinet Catal Lett 24, 253–257 (1984). https://doi.org/10.1007/BF02093437

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  • DOI: https://doi.org/10.1007/BF02093437

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