Skip to main content
SpringerLink
Log in

Dissociative adsorption of oxygen and hydrogen, and the formation of hydroxyl groups on the surface of Cu, Ag, Ni, Pd and Pt

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

By the semi-empirical interacting bonds method, the heats of oxygen and hydrogen adsorption in a dissociative form on the (100) face of Cu, Ag, Ni, Pd and Pt have been calculated. It has been shown that most stable are the multiply bonded adsorption forms. For the different bonding states, the heat of hydroxyl group formation from O2 and H2 varies but slightly. The calculated values are compared with the experimental data.

Abstract

Полуэмпирическим методом взаимодействующих связей рассчитаны теплоты адсорбции кислорода и водорода в атомарной форме на грани (100) Cu, Ag, Ni, Pd, Pt. Показано, что наиболее устойчивыми являюся многосвязные формы адсорбции. Для гидроксильных групп при переходе от одно-к многосвязным формам адсорбции надлюодается лишь незначительное увеличение в теплоте их образования из H2 и O2. Рассчитанные значения сопоставлены с зкспериментальными данными.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. N. N. Bulgakov, Yu. A. Borisov, V. V. Popovskii: Kinet. Katal.,14, 468 (1973).

    Google Scholar 

  2. V. A. Sobyanin, V. V. Gorodetskii, N. N. Bulgakov: React. Kinet. Catal. Lett.,3, 223 (1975).

    Google Scholar 

  3. V. P. Glushko: Termicheskie konstanty veschestv, Part I, Vol. VI. Moscow 1972: Part I, Vol. VII, Moscow 1974.

  4. G. B. Bokii: Vvedenie v kristallochimiyu. Izd. MGU, Moscow 1954.

    Google Scholar 

  5. V. I. Vladimirov, Sh. Kh. Khannokov: in Metallofizika,24, 22, Naukova Dumka 1968.

  6. N. A. Galaktionova: Vodorod v metallakh. Metallurgia, Moscow 1967.

    Google Scholar 

  7. S. Cerny, V. Ponec: Catal. Rev.,2, 249 (1969).

    Google Scholar 

  8. P. A. Kilty, W. M. H. Sachtler: Catal. Rev.,10, 1 (1974).

    Google Scholar 

  9. G. Ertl, J. Koch: Proc 5th Intern. Congr. Catalysis, Miami Beach, Florida 1972: Catalysis, Vol. II, p. 969, North-Holland 1973.

  10. G. Kneringer, F. P. Netzer: Surf. Sci.,49, 125 (1975).

    Google Scholar 

  11. L. S. Shield, W. W. Russel: J. Phys. Chem.,64, 1592 (1960).

    Google Scholar 

  12. P. R. Norton, P. J. Richards: Surf. Sci.,44, 129 (1974).

    Google Scholar 

  13. K. Christmann, O. Schober, M. Neumann: J. Chem. Phys.,60, 4528 (1974).

    Google Scholar 

  14. A. W. Aldag, L. D. Schmidt: J. Catal.,22, 260 (1971).

    Google Scholar 

  15. F. P. Netzer, G. Kneringer: Surf. Sci.,51, 526 (1975).

    Google Scholar 

  16. L. Mc Donnell, D. P. Woodruff, K. A. R. Mitchell: Surf. Sci.,45, 1 (1974).

    Google Scholar 

  17. H. H. Brongersma, J. B. Theeten: Surf. Sci.,54, 519 (1976).

    Google Scholar 

  18. W. H. Weinberg, R. P. Merrill: Surf. Sci.,33, 493 (1972).

    Google Scholar 

  19. G. Blyholder: J. Chem. Phys.,62, 3193 (1975).

    Google Scholar 

  20. A. V. Khasin, G. K. Boreskov: Kinet. Katal.,10, 613 (1969).

    Google Scholar 

  21. V. L. Kuchaev, M. I. Temkin: Kinet. Katal.,13, 1024 (1972).

    Google Scholar 

  22. B. A. Morrow, P. Ramamurthy: J. Phys. Chem.,77, 3052 (1973).

    Google Scholar 

  23. C. W. Jowett, P. J. Dobson, B. J. Hopkins: Surf. Sci.,17, 4745 (1969).

    Google Scholar 

  24. P. R. Norton: J. Catal.,36, 211 (1975).

    Google Scholar 

  25. V. Ponets: Problemy kinetiki i kataliza,14 10 (1970).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Catalysis, Novosibirsk, USSR

    V. A. Sobyanin, N. N. Bulgakov & V. V. Gorodetskii

Authors
  1. V. A. Sobyanin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. N. Bulgakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. V. Gorodetskii
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sobyanin, V.A., Bulgakov, N.N. & Gorodetskii, V.V. Dissociative adsorption of oxygen and hydrogen, and the formation of hydroxyl groups on the surface of Cu, Ag, Ni, Pd and Pt. React Kinet Catal Lett 6, 125–132 (1977). https://doi.org/10.1007/BF02084187

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02084187

Keywords

Search

Navigation