Abstract
Spectral manifestations of lateral interactions between molecules adsorbed on non-metallic adsorbents, mostly oxides are considered. Static interaction, repulsive or attractive can be distinguished from the dynamic or resonance dipole–dipole interaction (RDDI) by means of isotopic dilution. Analysis of spectral data on CO adsorbed at low temperatures on ZnO, some other oxides or halogenides as well as recent quantum chemical calculations shows that static effect is enhanced by the solid due to the effect of surface relaxation induced by adsorption. Computer modelling of static and dynamic interactions enable one to explain the structure of the bands of adsorbed CO, frequency shifts, and other details in the spectra. Attractive interactions between different molecules can lead to mutual enhancement of adsorption and to the phenomena of induced Brønsted acidity and basicity, or the superacidity of some oxides exposed to gaseous acids. The theory and new experimental data on the influence of RDDI on the band shape of adsorbed SF6 and CF4 are discussed. Spectral evidence for RDDI and vibrational energy transfer between NF3 and pre-adsorbed SF6 on ZnO is reported.
Similar content being viewed by others
References
Eischens RP, Francis A (1956) The effect of surface coverage on the spectra of chemisorbed CO. J Phys Chem 60:194–201
Boccuzzi F, Borello E, Zecchina A et al (1978) Infrared study of ZnO surface properties: I. Hydrogen and deuterium chemisorption at room temperature. J Catal 51:150–159. doi:10.1016/0021-9517(78)90288-9
Lavalley JC, Saussey J, Raïs T (1982) Infrared study of the interaction between CO and H2 on ZnO: mechanism and sites of formation of formyl species. J Mol Catal 17:289–298. doi:10.1016/0304-5102(82)85040-2
Hoffmann F (1983) Infrared reflection-absorption spectroscopy of adsorbed molecules. Surf Sci Rep 3:107. doi:10.1016/0167-5729(83)90001-8
Griffin GL, Yates J (1982) Coadsorption studies of CO and H2 on ZnO. J Chem Phys 77:3751–3758. doi:10.1063/1.444241
Denisenko LA, Tsyganenko AA, Filimonov VN (1984) Infrared study of the interaction between adsorbed molecules in the CO/ZnO system. React Kinet Catal Lett 25:23–26
Paukshtis EA, Soltanov RI, Yurchenko EN (1983) IR spectroscopic studies of low-temperature CO adsorption on CaNaY zeolite. React Kinet Catal Lett 22:147–151. doi:10.1007/BF02064823
Tsyganenko AA, Storozhev PY, Otero Areán C (2004) IR-spectroscopic study of the binding isomerism of adsorbed molecules. Kinet Catal 45:530–540. doi:10.1023/B:KICA.0000038081.43384.56
Garrone E, Bonelli B, Tsyganenko AA et al (2003) Spectroscopic and thermodynamic characterization of strontium carbonyls formed upon carbon monoxide adsorption on the zeolite Sr-Y. J Phys Chem B 107:2537–2542. doi:10.1021/jp0217841
Hadjiivanov K, Knözinger H (1999) FTIR spectroscopic evidence of formation of geminal dinitrogen species during the low-temperature N2 adsorption on NaY zeolites. Catal Lett 58:21–26. doi:10.1023/A:1019040825491
Hadjiivanov K (2000) FTIR study of low-temperature CO adsorption on Cu-ZSM-5: evidence of the formation of Cu2+(CO)2 species. J Catal 191:480–485. doi:10.1006/jcat.1999.2805
Hadjiivanov K, Ivanova E, Knözinger H (2003) FTIR study of low-temperature CO adsorption on Y zeolite exchanged with Be2+, Mg2+, Ca2+, Sr2+ and Ba2+ cations. Microporous Mesoporous Mater 58:225–236. doi:10.1016/S1387-1811(02)00650-9
Hadjiivanov K, Knözinger H (2009) Characterization of vacant coordination sites of cations on the surfaces of oxides and zeolites using infrared spectroscopy of adsorbed probe molecules. Surf Sci 603:1629–1636. doi:10.1016/j.susc.2008.09.052
Hadjiivanov K, Knözinger H, Ivanova E, Dimitrov L (2001) FTIR study of low-temperature CO and 15N2 adsorption on a CaNaY zeolite: formation of site-specified Ca2+(CO)3 and Ca2+(15N2)3 complexes. Phys Chem Chem Phys 3:2531–2536. doi:10.1039/b101782i
Tsyganenko AA, Denisenko LA, Zverev SM, Filimonov VN (1985) Infrared study of lateral interactions between carbon monoxide molecules adsorbed on oxide catalysts. J Catal 94:10–15
Scarano D, Spoto G, Bordiga S et al (1992) Lateral interactions in CO adlayers on prismatic ZnO faces: a FTIR and HRTEM study. Surf Sci 276:281–298. doi:10.1016/0039-6028(92)90716-J
Woodruff DP, Hayden BE, Prince K, Bradshaw AM (1982) Dipole coupling and chemical shifts in IRAS of CO adsorbed on Cu(110). Surf Sci 123:397–412. doi:10.1016/0039-6028(82)90336-3
Platero EE, Scarano D, Spoto G, Zecchina A (1985) Dipole coupling and chemical shifts of CO and NO adsorbed on oxides and halides with rock-salt structure. Faraday Discuss Chem Soc 80:183. doi:10.1039/dc9858000183
Lamberti C, Zecchina A, Groppo E, Bordiga S (2010) Probing the surfaces of heterogeneous catalysts by in situ IR spectroscopy. Chem Soc Rev 39:4951–5001. doi:10.1039/c0cs00117a
Hush NS, Williams ML (1974) Carbon monoxide bond length, force constant and infrared intensity variations in strong electric fields: valence-shell calculations, with applications to properties of adsorbed and complexed CO. J Mol Spectrosc 50:349–368
Hammaker RM, Francis SA, Eischens RP (1965) Infrared study of intermolecular interactions for carbon monoxide chemisorbed on platinum. Spectrochim Acta 21:1295–1309. doi:10.1016/0371-1951(65)80213-2
Tsyganenko AA, Zverev SM (1988) Mechanism of lateral interactions between molecules adsorbed on oxide surfaces. React Kinet Catal Lett 36:269–274. doi:10.1007/BF02063817
Lambert DK (1984) Stark effect of adsorbate vibrations. Solid State Commun 51:297–300. doi:10.1016/0038-1098(84)90691-4
de Lima ÍP, dos S Politi, Gargano R, Martins JBL (2015) Lateral interaction and spectroscopic constants of CO adsorbed on ZnO. Theor Chem Acc 134:1–8. doi:10.1007/s00214-015-1651-5
Silber D, Kowalski PM, Traeger F et al (2016) Adsorbate-induced lifting of substrate relaxation is a general mechanism governing titania surface chemistry. Nat Commun 7:12888. doi:10.1038/ncomms12888
Tsyganenko AA, Storozheva EN, Manoilova OV (2001) Manifestations of the acidity of adsorbed molecules in H-bonded complexes with silanol groups: Lewis acidity of ozone. Catal Today 70:59–71. doi:10.1016/S0920-5861(01)00407-2
Tsyganenko AA, Storozheva EN, Manoilova OV et al (2000) Brønsted acidity of silica silanol groups induced by adsorption of acids. Catal Lett 70:159–163. doi:10.1023/A:1018845519727
Storozheva EN, Sekushin VN, Tsyganenko AA (2006) FTIR spectroscopy evidence for the basicity induced by adsorption. Catal Lett 107:185–188. doi:10.1007/s10562-005-0008-4
Voronina KV, Tsyganenko AA (2009) FTIR evidence for Lewis acidity induced by adsorption. symposium “Molecular Photonics” dedicated to Academician A.N. Terenin, St. Petersburg, Russia, 2009 (abstract) p 163
Zaki MI, Knözinger H, Tesche B, Mekhemer GAH (2006) Influence of phosphonation and phosphation on surface acid-base and morphological properties of CaO as investigated by in situ FTIR spectroscopy and electron microscopy. J Colloid Interface Sci 303:9–17. doi:10.1016/j.jcis.2006.07.011
Lange F, Hadjiivanov K, Schmelz H, Knözinger H (1992) Low temperature infrared study of carbon monoxide adsorption on sulfated titania. Catal Letters 16:97–107. doi:10.1007/BF00764359
Lavalley JC, Saussey J, Tsyganenko AA (1994) IR study of interactions between different molecules CO-adsorbed on ZnO. Surf Sci 315:112–118. doi:10.1016/0039-6028(94)90547-9
Nichols H (1982) Dipole sums on a surface with fractional coverage: application to enhanced Raman spectra of halide ions on silver. J Chem Phys 76:5595. doi:10.1063/1.442864
Dai DJ, Ewing GE (1994) Vibrational overtone spectroscopy and coupling effects in monolayer CO on NaCl(100). Surf Sci 312:239–249. doi:10.1016/0039-6028(94)90822-2
Tsyganenko YA, Tsyganenko AA, Smirnov KS (1993) Fine features caused by lateral interactions in the infrared spectrum of CO adsorbed on ZnO (0 0). Vibr Spectrosc 6:15–23. doi:10.1016/0924-2031(93)87018-O
Ewing GE (1991) A model system for the study of structure and dynamics of molecules on surfaces: CO on NaCl(100). Intl Rev Phys Chem 10:391. doi:10.1080/01442359109353263
Heidberg J, Cabigon L, Kampshoff E, Kandel M (1993) In: Freund H-J, Umbach E (eds) Adsorption on ordered surfaces of ionic solids and thin films. Springer, New York, p 46
Noda C, Ewing GE (1990) Infrared spectroscopy of CO on NaCl(100) III. Submonolayers and isotopic mixtures. Surf Sci 240:181–192. doi:10.1016/0039-6028(90)90741-P
Tsyganenko YA, Ermoshin VA, Keyser MR et al (1996) Spectral manifestations of the dynamic interactions between adsorbed molecules. A computer modelling study. Vib Spectrosc 13:11–22. doi:10.1016/0924-2031(96)00016-1
Ermoshin VA, Kazanskii AK (1993) Modeling the collective vibrational excitations in CO isotope mixture adsorbed on Cu (100). Opt Spectrosc 75:1222–1229
Andrianov DS, Cherevatova AN, Kolomiitsova TD, Shchepkin DN (2009) Modeling of band shapes in the low-temperature molecular liquid spectra affected by resonance dipole-dipole interaction. Chem Phys 364:69–75. doi:10.1016/j.chemphys.2009.08.013
Dobrotvorskaia AN, Kolomiitsova TD, Petrov SN et al (2015) Effect of resonance dipole–dipole interaction on spectra of adsorbed SF6 molecules. Spectrochim Acta A 148:271–279. doi:10.1016/j.saa.2015.04.002
Burtsev AP, Bocharov VN, Gulidova OS et al (2008) The vibrational spectrum of the OCS molecule based on the data on spectra of liquid and cryosolutions. Opt Spectrosc 105:242–250. doi:10.1134/S0030400X08080122
Kolomiitsova TD, Lyaptsev AV, Shchepkin DN (2000) Determination of parameters of the dipole moment of the CO2 molecule. Opt Spectrosc 88:648–660
Kolomiitsova TD, Burtsev AP, Fedoseev VG, Shchepkin DN (1998) Manifestation of interaction of the transition dipole moments in IR spectra of low-temperature liquids and solutions in liquefied noble gases. Chem Phys 238:315–327
Kolomiitsova TD, Kondaurov VA, Sedelkova EV, Shchepkin DN (2002) Isotope effects in the vibrational spectrum of the SF6 molecule. Opt Spectrosc 92:512–516
Sverdlov LM, Kovner MA, Krainov EP (1974) Vibrational spectra of polyatomic molecules. Wiley, New York
Pearce HA, Sheppard N (1976) Possible Importave of a metal-surface selection rule in the interpretation og the infrared specta of molecules adsorbed on particulate metals. Surf Sci 59:205–217
Thomas P, Xia Y, Boyd DA et al (2009) Study of SF6 adsorption on graphite using infrared spectroscopy. J Chem Phys 131:124709. doi:10.1063/1.3226561
Dobrotvorskaia AN, Gatilova AV, Murzin PD et al (2017) Effect of resonance dipole-dipole interaction on the spectra of adsorbed CF4. J Photochem Photobiol A (in print)
Acknowledgements
The work was supported by a Grant of the Government of Russian Federation No 14.Z50.31.0016.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Dobrotvorskaia, A.N., Pestsov, O.S. & Tsyganenko, A.A. Lateral Interaction between Molecules Adsorbed on the Surfaces of Non-Metals. Top Catal 60, 1506–1521 (2017). https://doi.org/10.1007/s11244-017-0835-8
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11244-017-0835-8