Abstract
An analysis of the cross-combination ratio of the rate constants ϕ in terms of the statistical adiabatic channel model allows to factorize ϕ into two contributions: one due to the motion along the reaction coordinates and another due to the reaction transitional modes. ϕ for the CH3/CCl3, CH3/C2H3, CH3/C3H5, CH3/C2H5 and C2H5/C3H5 radical pairs were calculated.
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Cobos, C.J. A SACM study of the cross-combination ratio of rate constants. React Kinet Catal Lett 49, 167–171 (1993). https://doi.org/10.1007/BF02084044
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DOI: https://doi.org/10.1007/BF02084044