Abstract
The amounts of tetrahydrothiophene and octane have been determined in the hydrodesulfurization product of thiophene on molybdenum catalysts under various conditions. The results are interpreted as evidence for a consecutive reaction mechanism consisting of ring hydrogenation followed by decomposition of the saturated sulfur compound.
Abstract
Было определено количество тетрагидротиофена и октана в продуктах гидродесуль-фирования тиофена на молибденовых катализаторах при различных условиях. Результаты интерпретируются как доказательство механизма последовательных реакций гидрирования кольца с последующим разложением насыщенного серного соединения.
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References
P. J. Owens, C. H. Amberg: Adv. Chem. Ser.,33, 182 (1961).
P. Kieran, C. Kemball: J. Catal.,4, 394 (1965).
J. M. J. G. Lipsch, G. C. A. Schuit: J. Catal.,15, 179 (1969).
C. H. Amberg: J. Less-Common Metals,36, 339 (1974).
A. E. Hargreaves, J. R. H. Ross: Proc. Sixth Int. Congr. Catal., London 1976, Paper B 33.
M. Zdražil: Collect. Czech. Chem. Commun.,40, 3491 (1975).
M. Zdražil: Collect. Czech. Chem. Commun. (In press).
R. L. Smith, C. D. Prater: Chem. Eng. Progr., 63, Symp. Ser. No. 73, 105 (1967).
S. Landa, O. Weisser: Collect. Czech. Chem. Commun.,22, 93 (1957).
Amax Inc.: U. S. Appl. 427 487 (1973), API Patent Alert, No. 52, (1975).
S. Landa, A. Mrnková: Collect. Czech. Chem. Commun.,31, 2202 (1966).
P. B. Weisz: Adv. Catal.,13, 137 (1962).
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Kraus, J., Zdražil, M. Tetrahydrothiophene as intermediate in the hydrodesulfurization of thiophene. React Kinet Catal Lett 6, 475–480 (1977). https://doi.org/10.1007/BF02078731
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DOI: https://doi.org/10.1007/BF02078731