Abstract
The reaction of tetrahydrofuran with H2S catalyzed by acid-base catalysts has been studied. Catalysts containing an acid-base pair, i.e. a Lewis acid center and a base center, are the most active and selective towards thiolane. Proton donor catalysts and those containing only basic centers are of low activity and selectivity.
Abstract
Исследована реакция тетрагидрофурана с H2S в присутствии катализаторов кислотно-основного типа. Катализаторы, содержащие кислотно-основную пару: льюисовский кислотный центр-основный центр, наиболее активны и избирательны по тиолану. Протонодонорные катализаторы, а также содержащие только основные центры, низкоактивны и малоизбирательны.
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References
Yu. K. Yuriev: Catalysis in Higher Education, Part 2, p. 176, State University, Moskva 1962.
A. V. Mashkina, E. A. Paukshtis, V. N. Yakovleva: Kinet. Katal.,29, 596 (1988).
A. V. Mashkina, E. A. Paukshtis, V. N. Yakovleva: Kinet. Katal.,29, 1175 (1988).
A. V. Mashkina: Heterogeneous Catalysis in Chemistry of Organic Sulfur Compounds. Nauka, Novosibirsk 1977.
I. V. Desyatov, E. A. Paukshtis, A. V. Mashkina: React. Kinet. Catal. Lett., Vol. 41, No. 1, 85 (1990).
L. V. Malysheva: Thesis, Institute of Catalysis, Novosibirsk 1986.
H. G. Karge, J. Rasko: J. Colloid Interface Sci.,64, 522 (1978).
H. G. Karge, M. Ziolek, M. Laniecki: Zeolites,7, 197 (1987).
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Desyatov, I.V., Yakovleva, V.N. & Mashkina, A.V. Catalytic reaction of tetrahydrofuran with H2S. React Kinet Catal Lett 41, 97–102 (1990). https://doi.org/10.1007/BF02075488
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DOI: https://doi.org/10.1007/BF02075488