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Catalytic deamination on solid surfaces part 2.-Deamination of dicyclohexylamine on aluminium oxide

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Abstract

Deamination of dicyclohexylamine gives the same final products as those obtained from the respective primary amine on a similar surface. A theoretical rate equation derived permits the calculation of various rate constants from the experimental data. It is concluded that one of the intermediates formed from the two amines must be identical.

Abstract

Деаминирование дициклогексиламина дает те же самые конечные продукты, которые были получены из подобного первичного амина на подобной поверхности. Полученное теоретическое уравнение скорости позволяет рассчитать из экспериментальных данных различные константы скорости. Было заключено, что одии из промежуточных продуктов, поплчамых из двух аминов, должен быть идентичным.

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References

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Authors and Affiliations

  1. Physical Chemistry Laboratory, University of Patras, Patras, Greece

    G. Karaiskakis, A. Lycourghiotis, D. Vattis & N. A. Katsanos

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  1. G. Karaiskakis
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  2. A. Lycourghiotis
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  3. D. Vattis
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  4. N. A. Katsanos
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Karaiskakis, G., Lycourghiotis, A., Vattis, D. et al. Catalytic deamination on solid surfaces part 2.-Deamination of dicyclohexylamine on aluminium oxide. React Kinet Catal Lett 15, 413–418 (1981). https://doi.org/10.1007/BF02074143

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  • DOI: https://doi.org/10.1007/BF02074143

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