Skip to main content
SpringerLink
Log in

Effect of molybdenum ion coordination on acrolein adsorption on α- and β-cobalt molybdate

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

Arcolein adsorption on α- and β-polymorphous modifications of CoMoO4 has been studied by the thermal desorption technique. The effect of molybdenum coordination on the bond strength of surface acrolein compounds has been treated in terms of the interaction between frontier molecular orbitals of the active center and acrolein.

Abstract

Методом термодесорбции исследованы формы адсорбции акролеина на α и β-полиморфных модификациях CoMoO4 и в рамках взаимодействия граничных молекулярных орбиталей активного центра с акролеином рассмотрено влияние координации ионов молибдена на прочность связи образующихся поверхностных соединений акролеина с катализатором.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. V. Andrushkevich, G. Ya Popova, G. K. Boreskov, L. M. Plyasova, N. P. Boronina, G. K. Kustova: Kinet. Katal.,19, 184 (1978).

    Google Scholar 

  2. G. W. Smith, I. A. Iberes: Acta Crystallogr.,19, 269 (1965).

    Google Scholar 

  3. L. M. Plyasova, V. I. Zharkov, G. N. Kustova, L. G. Karakchiev, M. M. Andrushkevich: Izv. Akad. Nauk SSSR, Ser. Neorg. Mater.,9, 519 (1973).

    Google Scholar 

  4. G. K. Boreskov: Kinet. Katal.,14, 7 (1973).

    Google Scholar 

  5. G. Ya. Popova, A. A. Davydov, I. I. Zakharov, T. V. Andrushkevich: Kinet. Katal. (in press).

  6. V. G. Mikhalchenko, V. D. Sokolovskii, G. K. Boreskov: Kinet. Katal.,14, 698 (1973).

    Google Scholar 

  7. M. J. S. Dewar: Bull. Soc. Chim. Fr.,18, C17 (1951); J. Chatt, L. A. Duncanson: J. Chem. Soc., 2939 (1953).

    Google Scholar 

  8. M. Harberhold: π-Complexes of Metals. Mir, Moskva 1975.

    Google Scholar 

  9. V. I. Avdeev, I. I. Zakharov, V. A. Zakharov, G. D. Bukatov, Yu. I. Yermakov: Zh. Strukt. Khim.,18, 525 (1977).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Catalysis, Novosibirsk, USSR

    I. I. Zakharov, G. Ya. Popova & T. V. Andrushkevich

Authors
  1. I. I. Zakharov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. Ya. Popova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. V. Andrushkevich
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zakharov, I.I., Popova, G.Y. & Andrushkevich, T.V. Effect of molybdenum ion coordination on acrolein adsorption on α- and β-cobalt molybdate. React Kinet Catal Lett 19, 367–371 (1982). https://doi.org/10.1007/BF02074063

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02074063

Keywords

Search

Navigation