Abstract
The dependence of the stability of Mn(C5H7O2)3 modifications on the properties of the solvent chosen for recrystallization is considered. Low-polarity solvents with a low dielectric permittivity enhance intermolecular interactions, which leads to the formation of the β-Mn(C5H7O2)3 modification during the synthesis of Mn(C5H7O2)3 from chloroform solutions. The use of mixtures of chloroform with petroleum ether makes it possible to control supersaturation, the rate of formation, and growth of phase nuclei due to the evaporation of chloroform under isothermal conditions. The use of polar solvents for recrystallization favors the formation of γ-Mn(C5H7O2)3. The composition of the thermal decomposition products of β‑Mn(C5H7O2)3 in a dry inert atmosphere has been determined by X-ray powder diffraction, IR spectroscopy, thermogravimetric and mass spectral analysis, and differential scanning calorimetry. In the temperature range 140–240°C, β-Mn(C5H7O2)3 melts to form Mn(C5H7O2)2. At temperatures of 500–550°С, Mn(C5H7O2)2 decomposes to a mixture of MnO, Mn3O4, Mn2O3, and carbon.
Similar content being viewed by others
REFERENCES
B. B. Snider, Encyclopedia of Reagents for Organic Synthesis (John Wiley & Sons Ltd, 2001). https://doi.org/10.1002/047084289X.rm022
H. T. Ban, T. Kase, and M. Murata, J. Polym. Sci., Part A 39, 3733 (2001). https://doi.org/10.1002/pola.10021
R. Gorkum, E. Bouwman, and J. Reedijk, Inorg. Chem. 43, 2456 (2004). https://doi.org/10.1021/ic0354217
A. E. S. Sleightholme, A. A. Shinkle, Q. Liu, et al., J. Power Sources 196, 5742 (2011). https://doi.org/10.1016/j.jpowsour.2011.02.020
Y. J. Park, J. G. Kim, M. K. Kim, et al., Solid State Ionics 130, 203 (2000). https://doi.org/10.1016/S0167-2738(00)00551-8
J. P. Fackler and A. Avdeef, Inorg. Chem. 13, 1864 (1974). https://doi.org/10.1021/ic50138a016
B. R. Stults, R. S. Marianelli, and V. W. Day, Inorg. Chem. 18, 1853 (1979). https://doi.org/10.1021/ic50197a028
S. Geremia and N. Demitri, J. Chem. Educ. 82, 460 (2005). https://doi.org/10.1021/ed082p460
E. Arslan, R. A. Lalancette, and I. Bernal, Struct. Chem. 28, 201 (2017). https://doi.org/10.1007/s11224-016-0864-0
M. N. Bhattacharjee, M. K. Chaudhuri, and D. T. Khathing, J. Chem. Soc., Dalton Trans. 3, 669 (1982). https://doi.org/10.1039/DT9820000669
G. Kunstle, Patent FRG 2420775, 1974.
R. G. Charles and B. E. Bryant, Inorg. Synt. 183 (1963). https://doi.org/10.1002/9780470132388.ch49
G. H. Cartledge, US Patent 2556316, 1951.
W. Linke and G. Zirker, FRG Patent 1039056B, 1957.
F. Gach, C.R. Acad. Sci. Ser. IIc: Chim. 98 (1900).
V. I. Grachev, S. V. Noskov, and I. Yu. Filatov, RF Patent 2277529C1, Byull. Izobret. no. 16, 2006.
J. C. Matthews and L. L. Wood, US Patent 474464, 1969.
M. A. Siddiqi, R. A. Siddiqui, and B. Atakan, Surf. Coat. Tech. 201, 9055 (2007). https://doi.org/10.1016/j.surfcoat.2007.04.036
I. C. McNeill and J. J. Liggat, Polym. Degrad. Stab. 37, 25 (1992). https://doi.org/10.1016/0141-3910(92)90088-M
I. V. Babich, L. A. Davydenko, L. F. Sharanda, et al., Thermochim. Acta 456, 145 (2007).https://doi.org/10.1016/j.tca.2007.02.010
C. Reichert, G. M. Bancroft, and J. B. Westmore, Can. J. Chem. 48, 1362 (1970). https://doi.org/10.1139/v70-225
C. G. Macdonald and J. S. Shannon, Aust. J. Chem. 19, 1545 (1966). https://doi.org/10.1071/CH9661545
New Handbook of Chemist and Technologist, Ed. by A. V. Moskvina (St. Petersburg, 2006) [in Russian].
V. P. Zlomanov, R. S. Eshmakov, and I. V. Prolubshchikov, Condens. Matter Interphases 24, 29 (2022).
B. N. Tarasevich, IR Spectra of the Main Classes of Organic Compounds. Reference Materials (Moscow, 2012) [in Russian].
I. Diaz-Acosta, J. Baker, J. F. Hinton, et al., Spectrochim. Acta 59 Part A, 363 (2003). https://doi.org/10.1016/S1386-1425(02)00166-X
K. E. Lawson, Spectrochim. Acta 17, 248 (1961). https://doi.org/10.1016/0371-1951(61)80071-4
S. Pinchas, B. L. Silver, and I. Laulicht, J. Chem. Phys. 46, 1506 (1967). https://doi.org/10.1063/1.1840881
A. S. Alikhanyan, I. P. Malkerova, V. G. Sevast’yanov, et al., Vysokochist. Veshch. 3, 112 (1987).
P. P. Semyannikov, I. K. Igumenov, S. V. Trubin, and I. P. Asanov, J. Phys. IV. France 11, 995 (2001).
D. Jarosch, Mineral. Petrol. 37, 15 (1987). https://doi.org/10.1007/BF01163155
W. Hase, Phys. Status Solidi B 3, K446 (1963). https://doi.org/10.1002/pssb.19630031225
A. H. Jay and K. W. Andrews, J. Iron Steel I 152, 15 (1945).
O. Hassel and H. Mark, Z. Phys. 25, 317 (1924).
S. Shibata, S. Onuma, and H. Inoue, Inorg. Chem. 24, 1723 (1985). https://doi.org/10.1021/ic00205a028
M. van Tran, A. T. Ha, and P. M. L. Le, J. Nanomater. 16, 609273 (2015). https://doi.org/10.1155/2015/609273
E. W. Lemmon, M. O. McLinden, D. G. Friend, et al., National Institute of Standards and Technology (Gaithersburg, 2011).
Z. Wu, K. Yu, Y. Huang, et al., Chem. Cent. J. 1, 8 (2007). https://doi.org/10.1186/1752-153X-1-8
M. Sharrouf, R. Awad, M. Roumie, et al., Mater. Sci. Appl. 6, 850 (2015).
M. Zheng, H. Zhang, X. Gong, et al., Nanoscale Res. Lett. 8, 166 (2013). https://doi.org/10.1186/1556-276X-8-166
ACKNOWLEDGMENTS
The authors are grateful to prof., Dr. Sci. A.V. Yatsenko for X-ray powder diffraction analysis of single crystal and Cand. Sci. T.B. Shatalova for performing the TG procedure, MS analysis, and DSC (Department of Chemistry, Moscow State University).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare no conflicts of interest.
Additional information
Translated by V. Avdeeva
Rights and permissions
About this article
Cite this article
Eshmakov, R.S., Prolubshchikov, I.V. & Zlomanov, V.P. Synthesis and Thermal Stability of Manganese(III) Acetylacetonate. Russ. J. Inorg. Chem. 68, 50–59 (2023). https://doi.org/10.1134/S0036023622601799
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036023622601799