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Mössbauer spectroscopic studies of (n-C n H2n +1NH3)2SnCl6 (n=6, 8-18) complexes

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Abstract

Temperature-dependent Mössbauer experiments have been carried out to examine the lattice-dynamic properties of tin atoms in complexes of the type (n-C n H2n+1NH3)2SnCl6 (6 ≤n≤ 12). The temperature dependence of the area intensity of Mössbauer lines for the studied complexes are correlated to the motion of long alkyl chains. Solid-solid phase transitions were clearly found in all the complexes above room temperature, accompanied by an increase in the interlayer spacing (6≤n≤ 18). The transition temperature and transition entropy increase linearly with the number of carbon atoms in alkyl chains.

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Authors and Affiliations

  1. Radioisotope Research Center, Tokyo Metropolitan University, Hachioji, 192-03, Tokyo, Japan

    M. Katada

  2. Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, Hachioji, 192-03, Tokyo, Japan

    S. Nakai, T. Nakamoto & H. Sano

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  1. M. Katada
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  2. S. Nakai
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  3. T. Nakamoto
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  4. H. Sano
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Katada, M., Nakai, S., Nakamoto, T. et al. Mössbauer spectroscopic studies of (n-C n H2n +1NH3)2SnCl6 (n=6, 8-18) complexes. Hyperfine Interact 93, 1471–1475 (1994). https://doi.org/10.1007/BF02072895

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