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Goldanskii–Karyagin effect on hyperalkaline tin(II)-hydroxide

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Abstract

Frozen aqueous solution of hyperalkaline tin(II)-hydroxide was analysed by 119Sn Mössbauer spectroscopy at low temperature in order to determinate the structure of the hydroxo complex formed under hyperalkaline (pH > 13) conditions. Interestingly, the quadrupole doublet characteristic of this complex in the 119Sn Mössbauer spectrum exhibited asymmetry in the line intensities. Analysis of the temperature dependence of the Mössbauer spectra demonstrated that this phenomenon can be rationalised by the Goldanskii–Karyagin effect. The effect emerges due to the vibrational anisotropy of bonds in the tin complex formed in hyperalkaline solution, similarly to what has been found earlier for SnF2 with analogous Sn bond structure.

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Acknowledgments

Research leading to this contribution was supported by the National Research Fund of Hungary through OTKA 106234 and TÁMOP-4.2.2.C-11/1KONV-2012-0010.

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Authors and Affiliations

  1. Laboratory of Nuclear Chemistry, Institute of Chemistry, Eötvös Loránd University, Budapest, 1117, Hungary

    Attila Lengyel, Zoltán Homonnay & Ernő Kuzmann

  2. Institute of Materials and Environmental Chemistry, Research Centre for Natural Sciences, Hungarian Academy of Sciences, Budapest, 1117, Hungary

    Zoltán Klencsár

  3. Department of Inorganic and Analytical Chemistry, University of Szeged, Dóm tér 7, Szeged, 6720, Hungary

    Pál Sipos & Éva G. Bajnóczi

  4. Department of Organic Chemistry, University of Szeged, Dóm tér 8, Szeged, 6720, Hungary

    István Pálinkó

  5. Materials and Solution Structure Research Group, University of Szeged, Szeged, Hungary

    Pál Sipos, Éva G. Bajnóczi & István Pálinkó

Authors
  1. Attila Lengyel
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  2. Zoltán Klencsár
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  3. Zoltán Homonnay
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  4. Pál Sipos
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  5. Éva G. Bajnóczi
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  6. István Pálinkó
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  7. Ernő Kuzmann
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Correspondence to Ernő Kuzmann.

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Lengyel, A., Klencsár, Z., Homonnay, Z. et al. Goldanskii–Karyagin effect on hyperalkaline tin(II)-hydroxide. J Radioanal Nucl Chem 307, 1195–1201 (2016). https://doi.org/10.1007/s10967-015-4410-0

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  • DOI: https://doi.org/10.1007/s10967-015-4410-0

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