Abstract
The oscillatory behavior of the autooxidation of benzaldehyde catalyzed by cobalt(II) and bromide ions can be monitored besides potentiometry and/or spectrophotometry also by measuring the temperature of the reaction system and the pressure of oxygen above the solution as a function of time. The temperature and pressure oscillations can be explained only qualitatively so far.
Abstract
Осциллирующее поведение автоокисления бензальдегида, катализируемого ионами кобальта и брома, может быть детектировано, наряду с потенциометрическим и/или спектрофотометрическими методами, также измеряя температуру реакционной системы и давление кислорода над раствором в зависимсоти от времени. Пока колебания температуры и давления обьяснены лишь качественно.
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Marko, E., Treindl, Ľ. Temperature and pressure oscillations during the autooxidation of benzaldehyde. React Kinet Catal Lett 46, 345–349 (1992). https://doi.org/10.1007/BF02070956
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DOI: https://doi.org/10.1007/BF02070956