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Influence of HCl on butene isomerization catalyzed by ethanolic rhodium trichloride, I

Relationships between overall rate constant and HCl concentration

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Abstract

A study has been made of the influence of HCl on the kinetics of butene isomerization catalyzed by ethanolic rhodium trichloride over a wide range of HCl concentrations. Apparently HCl itself participates in the isomerization as a cocatalyst, and it shifts the equilibrium of the catalyst activation too. An equation for the description of the effect of HCl is suggested.

Abstract

Было исследовано влияние хлористого водорода на кинетику изомеризации бутена, катализированной RhCl3 · 3H2O в широкой области концентраций хлористого водорода. Очевидно сам HCl участвует в механизме изомеризации в виде кокатализатора. Кроме того HCl изменяет равновесие активации катализатора. Предлагается уравнение для описания действия хлористого водорода.

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Authors and Affiliations

  1. Sektion Chemie der Karl-Marx-Universität Leipzig, Linnéstr. 2, DDR-701, Leipzig, GDR

    J. Hoffmann

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  1. J. Hoffmann
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Hoffmann, J. Influence of HCl on butene isomerization catalyzed by ethanolic rhodium trichloride, I. React Kinet Catal Lett 9, 1–7 (1978). https://doi.org/10.1007/BF02070360

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  • DOI: https://doi.org/10.1007/BF02070360

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