Abstract
Applying IR spectroscopy for studying the Ziegler system Co(acac)3/Mg(Bu)2 (Bu=n-butyl) in tetrahydrofuran, it could be shown that the following reactions take place: reduction of cobalt (III), exchange of the acetylacetonate groups and their interaction with Mg(Bu)2.
Abstract
Исследуя систему Циглера Co(acac)3/Mg(Bu)2 (Bu=н-бутил) в тетрагидрофуране с помощью ИК-спектроскопии дыло показано, что происходит восстановление кобальта (III), смещение ацетилацетонатньх групп и их взаимодействне с Mg(Bu)2.
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Lühder, K., Böhmer, W.H., Stoldt, I. et al. An IR study of the Ziegler system Co(acad)3/Mg(n-butyl)2 in THF. React Kinet Catal Lett 48, 9–15 (1992). https://doi.org/10.1007/BF02070060
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DOI: https://doi.org/10.1007/BF02070060