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Catalytic properties of plantinized polycyanogens

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Abstract

The effect of various inorganic polymers on the catalytic activity and selectivity of platinum in the hydrogenation of 4-chloronitrobenzene and dinitrotoluene has been studied. Platinized iron-containing polycyanogens are less active but more selective catalysts for the hydrogenation of 4-chloronitrobenzene than Pt/C or Pt/BaSO4.

Abstract

Исследовано влияние различных неорганических полимеров на каталитическую активность и селективность платины в гидрогенизации 4-хлорнитробенэола и динитротолуола. Платинированные полицианогены, содержащие железо, являются менее активными, но более селективными катализаторами гидрогенизации 4-хлорнитробензола, по сравнению с Pt/C или Pt/BaSO4.

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References

  1. T.V. Denisenko, V.I. Savcenko, V.D. Simonov, C.Ya. Sklar: Zh. Org. Khim.,18, 1498 (1982).

    Google Scholar 

  2. R.J. Peterson: Hydrogenation Catalysts, p. 256 Noyes Data Corporation, Park Ridge, New Jersey, 1977.

    Google Scholar 

  3. W.H. Jones: Catalysis in Organic Syntheses, p. 107. Academic Press, New York-London-Sydney-Toronto-San Francisco, 1980.

    Google Scholar 

  4. H. Kritzler, W. Boehm, W. Kiel, U. Birkenstock: Ger. Offen. 2,549,900 (1975). Chem. Abstr.87:134464.

  5. J.D. Hildreth, D.G. Haslam: Eur. Pat. Appl. 0.805 (1977). Chem. Abstr.91:211059.

  6. A. Mills: J.C.S. Chem. Commun., 367 (1982).

  7. M. Labadie, R. Jensen, E. Neuzil: Biochim. Biophys. Acta,165, 525 (1968).

    Google Scholar 

  8. Z. Tóth, J. Gulyás, M.T. Beck: Inorg. Chim. Acta.,113, 67 (1986).

    Google Scholar 

  9. L.L. Bircumshaw, F.M. Tayler, D.H. Whiffen: J. Chem. Soc., 931 (1954).

  10. V.S. Yakovlev: Ukr. Khim. Zh.,31, 113 (1965).

    Google Scholar 

  11. Z. Tóth, M.T. Beck: to be published

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Authors and Affiliations

  1. Institute of Physical Chemistry, Department of Chemistry, Kossuth Lajos University, H-4010, Debrecen, Hungary

    Z. Tóth & A. Erdelics-Dobi

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  1. Z. Tóth
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  2. A. Erdelics-Dobi
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Tóth, Z., Erdelics-Dobi, A. Catalytic properties of plantinized polycyanogens. React Kinet Catal Lett 34, 117–122 (1987). https://doi.org/10.1007/BF02069211

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  • DOI: https://doi.org/10.1007/BF02069211

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