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Effect of ligands on the hydrogenation selectivity in the presence of rhenium catalysts

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Abstract

It has been established that the catalytic activity of rhenium oxohalide complexes with phosphorus- or sulfur-containing ligands in hydroganation of C6−C10 olefins, nitrobenzene and p-nitrotoluene is primarily determined by the original ligand to rhenium ion bond. Chain length of olefins does not affect their hydrogenation rate.

Abstract

Каталитическая активность рениевых оксогалогенидных комплексов с фосфор- или серосодержащими лигандами в реакциях гидрирования олефинов C6−C10, нитробензола и п-нитротолуола определяется прежде всего прнродой связи рений-лнганд в исходном комцлексе. Длина цепи олефинов не влияет на скорость их гидрнрования.

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References

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Authors and Affiliations

  1. Institute of Physical Chemistry, 252028, Kiev, USSR

    V. M. Belousov, T. A. Palchevskaya & L. A. Zyuzya

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  1. V. M. Belousov
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  2. T. A. Palchevskaya
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  3. L. A. Zyuzya
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Belousov, V.M., Palchevskaya, T.A. & Zyuzya, L.A. Effect of ligands on the hydrogenation selectivity in the presence of rhenium catalysts. React Kinet Catal Lett 34, 41–44 (1987). https://doi.org/10.1007/BF02069198

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  • DOI: https://doi.org/10.1007/BF02069198

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