Abstract
Dy2O3 activated at high temperature is reported as a catalyst for the liquid phase reduction of cyclohexanone. The catalytic activity of Dy2O3 activated at 300, 500 and 800°C and its mixed oxides with alumina for the reduction of cyclohexanone with 2-propanol has been reported. The data have been correlated with the electron donating properties of the catalysts which were reported from the adsorption of electron acceptors [EA] of various electron affinity on the surface of these oxides.
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K. D. Campbell, H. Zhang, J. H. Lunsford: J. Phys. Chem.,92, 750 (1988).
T. Arai, K. Maruya, K. Domen, T. Onishi: Bull. Chem. Soc. Jpn.,62, 349 (1989).
S. Sugunan, K. B. Sherly, G. Devika Rani: React. Kinet. Catal. Lett.,51, 525 (1993).
F. Le Normand, J. Barrault, R. Breault, L. Hilaire, A. Kiennemann: J. Phys. Chem.,95, 257 (1991).
E. Rodenas, H. Hattori, I. Toyoshima: React. Kinet. Catal. Lett.,16, 73 (1981).
S. Sugunan, G. Devika Rani, K. B. Sherly: React. Kinet. Catal. Lett.,43, 375 (1991).
S. Sugunan, G. Devika Rani:J. Mat. Sci. Lett.,10, 887 (1991).
S. Sugunan, G. Devika Rani: J. Mat. Sci. Lett.,11, 1269 (1992).
S. Sugunan, G. Devika Rani: J. Mat. Sci., (in press).
S. Sugunan, K. B. Sherly: Indian J. Chem. (in press).
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Sugunan, S., Sherly, K.B. Dy2O3 as a catalyst for a Meerwein-Ponndorf-Verley reaction. React Kinet Catal Lett 51, 533–539 (1993). https://doi.org/10.1007/BF02069101
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DOI: https://doi.org/10.1007/BF02069101