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Gas-phase hydroformylation of propylene on Ru/SiO2 catalysts

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Abstract

Ru/SiO2 catalysts prepared by reduction of supported RuCl3·xH2O are active in gas-phase hydroformylation of propylene at low pressure (ca. 0.3 MPa) of H2+CO+C3H6 mixtured and show unexpectedly high selectivity towards unbranched oxo-products. Data concerning the effect of electronic state and dispersity of Ru on their catalytic behavior have been obtained.

Abstract

Катализаторы Ru/SiO2, приготовленные восстановлением нанесенного RuCl3·xH2O, активны в реакции газофазного гидроформилирования пропилена при низких (∼0,3 МПа) давлениях реакционной смеси и проявляют неожиданно высокую селективность в образовании оксо-продуктов линйного строения. Получены данные о влиянии состояния и дисперсности рутения на свойства щтих катализаторов.

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Authors and Affiliations

  1. Central Salt and Marine Chemicals Research Institute, 364002, Bhavnagar, India

    S. B. Halligudi & M. M. Taqui Khan

  2. Institute of Catalysis, 630090, Novosibirsk, USSR

    B. L. Moroz, A. L. Chuvilin, I. P. Prosvirin & V. A. Likholobov

Authors
  1. S. B. Halligudi
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  2. M. M. Taqui Khan
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  3. B. L. Moroz
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  4. A. L. Chuvilin
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  5. I. P. Prosvirin
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  6. V. A. Likholobov
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Halligudi, S.B., Taqui Khan, M.M., Moroz, B.L. et al. Gas-phase hydroformylation of propylene on Ru/SiO2 catalysts. React Kinet Catal Lett 44, 139–146 (1991). https://doi.org/10.1007/BF02068397

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  • DOI: https://doi.org/10.1007/BF02068397

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