Skip to main content
SpringerLink
Log in

Catalytic properties of V−Mo−O systems in acrolein oxidation

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

Catalytic properties of V−Mo−O systems have been studied in acrolein oxidation. When catalysts are activated in reaction mixtures at 673 K, then a solid solution of molybdenum oxides in reduced vanadium oxides is formed, which is responsible for deep oxidation. Also, several compounds are produced, which by their activity and selectivity to acrylic acid formation are arranged in the sequences VMo3O11≅VMo2O8+x>V6Mo4O25, and VMo3O11>VMo2O8+x≫V6Mo4O25, respectively.

Abstract

В реакции окисления акролеина исследована V−Mo−O система. При формировании катализаторов при 673 K в реакционной смеси в системе образуются твердый раствор оксидов молибдена в восстановленных оксидах ванадия, который катализирует в основном глубокое окисление, и ряд химических соединений, которые по активности располагаются в ряд: VMo3O11≈VMo2O8+x>V6Mo4O25, а по селективности в реакции образования акриловой кислоты: VMo3O11>VMo2O8+x≫V6Mo4O25.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T.V. Andrushkevich, L.M. Plyasova, T.G. Kuznetsova, V.M. Bondareva, T.P. Gorshkova, I.P. Olenkova, N.I. Lebedeva: React.Kinet.Catal.Lett.,12, 463 (1979)

    Google Scholar 

  2. T.G. Kuznetsova, G.K. Boreskov, T.V. Andrushkevich, L.M. Plyasova, N.G. Maksimov, I.P. Olenkova: React.Kinet.Catal. Lett.,12, 531 (1979)

    Google Scholar 

  3. T.G. Kuznetsova: Thesis, Institut Kataliza, Novosibirsk 1984.

  4. I.P. Olenkova: Thesis, Institut Kataliza, Novosibirsk 1982.

  5. L.M. Plyasova, G.A. Zenkovets, I.P. Olenkova, D.V. Tarasova: Izv.Sib.Otd.Akad.Nauk SSSR, Ser.Khim.,15, 97 (1980)

    Google Scholar 

  6. X-Ray PDF ASTM, 19-1398, Philadelphia, 1964.

  7. X-Ray PDF ASTM, 19-1399, Philadelphia, 1964.

  8. M.M. Nolf: Thesis Doct. Ing.Fac.Sci., University, Lille, 1966

  9. A.A. Davydov, T.G. Kuznetsova, T.V. Andrushkevich: React. Kinet.Catal.Lett.,30, 173 (1986)

    Google Scholar 

  10. G.Ya. Popova, A.A. Davydov, I.I. Zakharov, T.V. Andrushkevich: Kinet.Katal.,23, 692 (1982)

    Google Scholar 

  11. T.P. Gorshkova, D.V. Tarasova, T.V. Andrushkevich, I.P. Olenkova, V.M. Bondareva, L.M. Plyasova, N.G. Maksimov: Kinet.Katal.,22, 497 (1981)

    Google Scholar 

  12. N.N. Chumachenko, D.V. Tarasova, T.A. Nikoro, I.V. Yaroslavtseva: Kinet.Katal.,25, 659 (1984)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Catalysis, 630090, Novosibirsk, USSR

    T. G. Kuznetsova, T. V. Andrushkevich & T. P. Gorshkova

Authors
  1. T. G. Kuznetsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. V. Andrushkevich
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. P. Gorshkova
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kuznetsova, T.G., Andrushkevich, T.V. & Gorshkova, T.P. Catalytic properties of V−Mo−O systems in acrolein oxidation. React Kinet Catal Lett 30, 149–156 (1986). https://doi.org/10.1007/BF02068159

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02068159

Keywords

Search

Navigation