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Kinetics and catalysis by NaY entrapped Pt carbonyl clusters in the CO+NO reaction

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Abstract

[Pt12(CO)24]2−/NaY and [Pt9(CO)18]2−/NaY exhibited much higher activities in the CO+NO reaction at 473 K compared with Pt/Al2O3. Kinetic study andin-situ FTIR results suggest that NO adsorption is the rate-limiting step in the CO+NO reaction on intrazeolite Pt carbonyl clusters.

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Authors and Affiliations

  1. State Key laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 116023, Dalian, China

    Guangjin Li & Xiexian Guo

  2. Catalysis Research Center, Hokkaido University, 060, Sapporo, Japan

    Masaru Ichikawa

Authors
  1. Guangjin Li
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  2. Masaru Ichikawa
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  3. Xiexian Guo
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Li, G., Ichikawa, M. & Guo, X. Kinetics and catalysis by NaY entrapped Pt carbonyl clusters in the CO+NO reaction. React Kinet Catal Lett 59, 75–86 (1996). https://doi.org/10.1007/BF02067995

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  • DOI: https://doi.org/10.1007/BF02067995

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