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Influence of the structure of monoalkyl substituted ketenes upon the rate of their spontaneous hydrolysis in water

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Abstract

The kinetics of spontaneous hydrolysis of monoalkylsubstituted ketenes has been studied. The influence of inductive and steric effects of substituents upon the rate has been quantitatively estimated in terms of ρσ-analysis. Increasing length and branching of alkyl substiuents decrease the rate of ketene hydrolysis.

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Authors and Affiliations

  1. Institute of Physical Organic and Coal Chemistry of the Ukrainian Academy of Sciences, 340114, Donets, Ukraine

    S. N. Lyashchuk & Yu. G. Skrypnik

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  1. S. N. Lyashchuk
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  2. Yu. G. Skrypnik
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Lyashchuk, S.N., Skrypnik, Y.G. Influence of the structure of monoalkyl substituted ketenes upon the rate of their spontaneous hydrolysis in water. React Kinet Catal Lett 52, 399–404 (1994). https://doi.org/10.1007/BF02067814

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  • DOI: https://doi.org/10.1007/BF02067814

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