Abstract
Reoxidation by carbon dioxide and reduction by methane of modified manganese and magnesium oxides have been studied. Surface oxidation has an optimum degree for reoxidation of manganese systems by carbon dioxide in contrast to that by oxygen. This leads to a higher selectivity towards C2 hydrocarbons in the reduction of manganese oxide by methane.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A. Kh. Mamedov, S. R. Mirzabekova, Sh. A. Nuriyev, P. A. Shiryaev, D. P. Shashkin: Neftekhimiya,30, 30 (1990).
A. Kh. Mamedov, P. A. Shiryaev, D. P. Shashkin, O. V. Krylov: Proc. 1st World Congress: New Development in Selective Oxidation, Rimini, 1989, p. 477, Elsevier, Amsterdam, 1990.
T. Ito, Ji-X. Wang, C. H. Lin, J. H. Lunsford: J. Am. Chem. Soc.,107, 5062 (1985).
G. K. Boreskov: Heterogeneous Catalysts, Nauka, Moscow 1986.
T. Le Van, M. Che, M. Kormars, C. Louic, J. M. Totibouet: Catal. Lett.,395, 3 (1990).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Mirzabekova, S.R., Mamedov, A.K. & Aliev, V.S. Reoxidation of modified manganese and magnesium oxides by carbon dioxide. React Kinet Catal Lett 52, 309–316 (1994). https://doi.org/10.1007/BF02067803
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02067803