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Manganese Catalysts for the Ozone-Assisted Oxidation of Volatile Organic Compounds: Effect of the Mn3+/Mn4+ Active Site Ratio on Catalytic Properties

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Abstract

The catalytic properties of supported Mn/carrier catalysts (carriers: Al2O3, SiO2, SiO2–Al2O3) in the ozone-assisted oxidation of volatile organic compounds (using the example of n-С4Н10) in a temperature range of 25–350°С have been studied. X-ray diffraction analysis and H2-TPR have shown that the carrier has a significant effect on the valence state of manganese in the supported oxide: on the SiO2 surface, manganese is present mostly in the form of Mn3+ (Mn2O3, Mn3O4), whereas in the Mn/Al2O3 and Mn/SiO2–Al2O3 catalysts the dominant species is Mn4+ (MnO2). Comparison of data on the composition of MnOx active phases and catalytic properties in the ozone-assisted oxidation of n-С4Н10 has revealed that an increase in the content of Mn3+sites contributes to an enhancement of the catalytic activity of Mn/support. However, an excess amount of Mn3+ leads to the consumption of ozone in a side reaction to form O2, which leads to a significant decrease in the n-С4Н10 oxidation efficiency. The data suggest that the maximum activity of the catalyst in the ozone-assisted oxidation of n-С4Н10 can be achieved via providing an optimum Mn3+/Mn4+ ratio.

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Authors and Affiliations

  1. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. I. Mytareva, I. S. Mashkovsky, D. A. Bokarev, G. N. Baeva, S. A. Kanaev, A. V. Kazakov & A. Yu. Stakheev

  2. Higher Chemical College, Russian Academy of Sciences, Mendeleev University of Chemical Technology of Russia, 125047, Moscow, Russia

    A. S. Gilev

Authors
  1. A. I. Mytareva
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  2. A. S. Gilev
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  3. I. S. Mashkovsky
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  4. D. A. Bokarev
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  5. G. N. Baeva
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  6. S. A. Kanaev
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  7. A. V. Kazakov
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  8. A. Yu. Stakheev
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Correspondence to A. I. Mytareva.

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Translated by M. Timoshinina

Abbreviations and notation: VOCs, volatile organic compounds; XRD, X-ray diffraction analysis; H2-TPR, temperature-programmed reduction with hydrogen; CSR, coherent scattering region.

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Mytareva, A.I., Gilev, A.S., Mashkovsky, I.S. et al. Manganese Catalysts for the Ozone-Assisted Oxidation of Volatile Organic Compounds: Effect of the Mn3+/Mn4+ Active Site Ratio on Catalytic Properties. Kinet Catal 63, 515–522 (2022). https://doi.org/10.1134/S0023158422050081

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