Abstract
The synthesis of CH2(OC4H9)2 by phase transfer catalysis (PTC) has been studied in C6H5Cl/KOH solution. A pseudo-first-order rate law was applied for describing the reaction at a rather high [KOH]w. The reaction system was limited by the reaction equilibrium in the aqueous phase at low [KOH]w and the reaction in the organic phase at high [KOH]w.
Similar content being viewed by others
References
H. H. Freedman: Pure Appl. Chem.,58, 857 (1986).
C. M. Starks: Am. Chem. Soc. Symp.,326, 1 (1985).
E. V. Dehmlow, J. Schmidt: Tetrahedron Lett.,2, 95 (1982).
A. F. Lopez, M. T. Peralta de Arija, O. A. Orio: J. High Resol. Chromatog.,12, 503 (1989).
D. Landini, A. Maia, G. Podda: J. Org. Chem.,47, 2264 (1982).
C. L. Liotta, E. M. Burgess, C. C. Ray, E. D. Black, B. E. Fair: ACS Symp.,326, 15 (1986).
M. L. Wang, H. M. Yang: Chem. Eng. Sci.,46, 619 (1990).
J. March: Advanced Organic Chemistry, 3rd Ed., p. 220, John Wiley & Sons, New York 1985.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Wang, ML., Chang, SW. Mechanism and kinetics of synthesizing dibutoxymethane by phase transfer catalysis. React Kinet Catal Lett 49, 333–337 (1993). https://doi.org/10.1007/BF02067700
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02067700