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Desorption parameters in the synthesis of 2-methylpyrazine over Zn−Cr−O

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Abstract

Desorption activation energy of both reactants and products was found to be only slightly higher than the desorption enthalpy and, for reactants, it was higher than the activation energy for the title reaction. Methylpyrazine desorbs much more easily than reactants.

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References

  1. L. Forni: J. Catal.,111, 199 (1988).

    Google Scholar 

  2. L. Forni, S. Nestoi: in M. Guisnet, J. Barrault, C. Bouchoule, D. Duprez, C. Montassier and G. Pérot (Editors), Heterogeneous Catalysis and Fine Chemicals, Studies in Surface Science and Catalysis, Vol. 41, p. 291. Elsevier, Amsterdam 1988.

    Google Scholar 

  3. L. Forni, R. Miglio: in M. Guisnet, J. Barrault, C. Bouchoule, D. Duprez, G. Pérot, R. Maurel and G. Montassier (Editors), Heterogeneous Catalysis and Fine Chemicals II Studies in Surface Science and Catalysis, Vol. 59, p. 367. Elsevier, Amsterdam 1991.

    Google Scholar 

  4. L. Forni, P. Pollesel: J. Catal.,130, 403 (1991).

    Google Scholar 

  5. L. Forni, V. Y. Tugarinov, C. Oliva, A. V. Vishniakov, F. P. Vatti: J. Mater. Sci., in press

  6. Selected Powder Diffraction Data, vol. 1–40, JCPDS, Swarthmore, PA, 1974–1992.

  7. L. Forni, M. Toscano, P. Pollesel: J. Catal.,130, 392 (1991).

    Google Scholar 

  8. S.R. Heller, G.W.A. Milne: EPA-NIH Mass Spectral Data Base, Vol. 1 and 5. U.S. Government Printing Office, National Bureau of Standards, Washington, D.C., 1978.

    Google Scholar 

  9. R.J. Cvetanovic, Y. Amenomiya: Adv. Catal. (D.D. Eley, P.W. Selwood and P.B. Weisz, Eds.), Vol. 17, p. 103. Academic Press, New York 1967.

    Google Scholar 

  10. L. Forni, R. Miglio: Paper accepted for presentation at the 3rd Intern. Symp. on Heterogeneous Catalysis and Fine Chemicals, Poitiers (France), April 1993.

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Authors and Affiliations

  1. Dipartimento di Chimica Fisica ed Elettrochimica, Universita' di Milano, via C. Golgi, 19 20133, Milano, Italy

    Lucio Forni, Francesco P. Vatti & Cesare Oliva

  2. Mendeleev Institute of Chemical Technology, Miusskaya Sq. 9, Moscow, Russia

    Vitalii Y. Tugarinov & Anatolii V. Vishnyakov

Authors
  1. Lucio Forni
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  2. Vitalii Y. Tugarinov
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  3. Francesco P. Vatti
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  4. Cesare Oliva
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  5. Anatolii V. Vishnyakov
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Forni, L., Tugarinov, V.Y., Vatti, F.P. et al. Desorption parameters in the synthesis of 2-methylpyrazine over Zn−Cr−O. React Kinet Catal Lett 49, 271–278 (1993). https://doi.org/10.1007/BF02067691

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  • DOI: https://doi.org/10.1007/BF02067691

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