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Activation of hydrocarbons in the oxidative dimerization of methane over alkaline earth metals

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Abstract

Oxidative dimerization of methane over alkaline earth metal oxides and phosphates has been studied. The ratedetermining step is heterolytic C−H bond dissociation of methane on surface basic sites of the catalysts.

Abstract

Изучена окислительная димеризация метана на окислах и фосфатах щелочно-земельных металлов. Показано, что лимитирующей стадией реакции является гетеролитический разрыв C−H связи метана на основных центрах поверхности контакта.

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Authors and Affiliations

  1. Institute of Catalysis, 630090, Novosibirsk, USSR

    O. V. Buevskaya, A. I. Suleimanov, S. M. Aliev & V. D. Sokolovskii

Authors
  1. O. V. Buevskaya
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  2. A. I. Suleimanov
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  3. S. M. Aliev
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  4. V. D. Sokolovskii
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Buevskaya, O.V., Suleimanov, A.I., Aliev, S.M. et al. Activation of hydrocarbons in the oxidative dimerization of methane over alkaline earth metals. React Kinet Catal Lett 33, 223–227 (1987). https://doi.org/10.1007/BF02066728

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  • DOI: https://doi.org/10.1007/BF02066728

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