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Mechanism of isotope exchange of dihydrogen with liquid ammonia catalyzed, by amide ions

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Abstract

The interacting bonds method (IBM) has been used for the analysis of hydrogen bonds in liquid ammonia, including estimates of the “resonance” components of the H=bonds of ammonia molecules with ammonium and amide ions. According to the Ea estimates for the interaction of a hydrogen molecule with an amide-ammonia solution (AAS) and the data on liquid ammonia structure, a kinetic mechanism for isotope exchange (IE) of hydrogen with liquid ammonia is formulated.

Abstract

Метод взаимодействующих связей (MBC) применён к анализу водородных связей в жидком аммиаке, включая оценки „резонансных” компонент Н-связей, молекул аммиака с аммоний-и амид-ионаи. Получены оценки Ea для взаимодействий молекулх водорода с амидо-аммиачным раствором (AAP). На основе этих оценок и данных о структуре жидкого аммиака сформулирована кинетеческая схема механизма изотопного обмена (ИО) водорода с жидким аммиаком.

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Authors and Affiliations

  1. Polytechnical Institute, Tomsk, USSR

    A. A. Medvinskii, N. N. Bulgakov & Y. M. Baikov

  2. Institute of Catalysis, Novosibirsk, USSR

    A. A. Medvinskii, N. N. Bulgakov & Y. M. Baikov

  3. Physico-Technical Institute, Leningrad, USSR

    A. A. Medvinskii, N. N. Bulgakov & Y. M. Baikov

Authors
  1. A. A. Medvinskii
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  2. N. N. Bulgakov
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  3. Y. M. Baikov
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Medvinskii, A.A., Bulgakov, N.N. & Baikov, Y.M. Mechanism of isotope exchange of dihydrogen with liquid ammonia catalyzed, by amide ions. React Kinet Catal Lett 20, 267–271 (1982). https://doi.org/10.1007/BF02066308

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  • DOI: https://doi.org/10.1007/BF02066308

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