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Silica-immobilized binuclear chromium-molybdenum complexes

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Abstract

ESR and UV spectra of a binuclear complex [n-(C4H9)4N]3 CrMoOCl9 in solution and supported on SiO2 have been studied. Upon fixing this complex followed by oxidation-reduction treatment, a highly disperse state is observed, as evidenced by the ESR spectra of the Cr3+ ions.

Abstract

Исследованы ЭПР и УФ спектры биядерного комплекса [H−(C4H9)4N]3CrMoOCl9 в растворе и при нанесении на SiO2. При закреплении комплекса с последующими окислительно-восстаиовительными обработками наблюдается высоко диспергированное состояние, на что указывают характерные спектры ЭПР ионов Cr3+.

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Authors and Affiliations

  1. Institute of Catalysis, Novosibirsk, USSR

    E. G. Ismailov, S. M. Aliev & V. D. Sokolovskii

  2. Institute of Petrochemical Processes, Baku, USSR

    O. V. Buevskaya

Authors
  1. O. V. Buevskaya
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  2. E. G. Ismailov
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  3. S. M. Aliev
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  4. V. D. Sokolovskii
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Buevskaya, O.V., Ismailov, E.G., Aliev, S.M. et al. Silica-immobilized binuclear chromium-molybdenum complexes. React Kinet Catal Lett 22, 345–350 (1983). https://doi.org/10.1007/BF02066200

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  • DOI: https://doi.org/10.1007/BF02066200

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