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Reaction of the muonium substituted cyclohexadienyl radical with 2,3-dimethyl-1,3,-butadiene

  • Muonium Radical Formation and Chemical Reactions
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Abstract

The rate constant for the title reaction is represented by log (k M/M−1s−1)=6.9(4)−700(350)K/T between 279 and 343K, whereas the H analogous radical, C6H7, reacts at room temperature withk H 12 M−1s−1 with dimethylbutadiene. The title reaction is proposed to be transfer of the light hydrogen isotope, Mu, and the large kinetic isotope effect is discussed.

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References

  1. D.G. Fleming, D.M. Garner, L.C. Vaz, D.C. Walker, J.H. Brewer, and K.M. Crowe, Adv. Chem. Ser., No.175 (1979) 279

    Google Scholar 

  2. P.W. Percival, E. Roduner, and H. Fischer, Adv. Chem. Ser., No.175 (1979) 335

    Google Scholar 

  3. D.C. Walker, J. Phys. Chem.85 (1981) 3960

    Google Scholar 

  4. E. Roduner. W. Strub, P. Burkhard, J. Hochmann, P.W. Percival, H. Fischer, M. Ramos, and B.C. Webster, Chem. Phys.67 (1982) 275

    Google Scholar 

  5. E. Roduner, G.A. Brinkman, and P.W.F. Louwrier, Chem. Phys.73 (1982) 117

    Google Scholar 

  6. E. Roduner, G.A. Brinkman, and P.W.F. Louwrier, Hyperfine Interactions17–19 (1984) 797; H. Fischer, this conference, p. 751

    Google Scholar 

  7. E. Roduner and H. Fischer, Chem. Phys.54 (1981) 261

    Google Scholar 

  8. H.R. Dütsch and H. Fischer, Int. J. Chem. Kinetics13 (1981) 527

    Google Scholar 

  9. R.W. Fessenden and R.H. Schuler, J. Chem. Phys.38 (1963) 773

    Google Scholar 

  10. J.A. Kerr and M.S. Parsonage, in: Evaluated Kinetic Data on Gas Phase Addition Reactions (Butterworths, Birmingham, 1972)

    Google Scholar 

  11. G. Brunton, D. Griller, L.R.C. Barclay, and K.U. Ingold, J. Amer. Chem. Soc.98 (1976) 6803

    Google Scholar 

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Authors and Affiliations

  1. Physikalisch-Chemisches Institut der Universität Zürich, Winterthurerstrasse 190, CH-8057, Zürich, Switzerland

    E. Roduner & K. Münger

Authors
  1. E. Roduner
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  2. K. Münger
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Support by the Swiss National Foundation for Scientific Research and by the Swiss Institute for Nuclear Research (SIN) are gratefully acknowledged.

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Roduner, E., Münger, K. Reaction of the muonium substituted cyclohexadienyl radical with 2,3-dimethyl-1,3,-butadiene. Hyperfine Interact 19, 793–796 (1984). https://doi.org/10.1007/BF02066122

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  • DOI: https://doi.org/10.1007/BF02066122

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