Abstract
Selective catalytic reduction (SCR) of nitric oxide in an oxygen-rich atmosphere with propylene as a reductant has been investigated over supported La-Co-oxide (mixed metal oxide) catalysts prepared by the modified citrate method. Loading on ZSM-5 support gave greatly enhanced activity in the reduction of NO at relatively low temperatures. This SCR activity could be ascribed to incorporation of the mixed metal oxide into ZSM-5 as an amorphous perovskite phase via preparation.
Similar content being viewed by others
References
M. Shelef:Chem. Rev.,95, 209 (1995).
S. M. Cho:Chem. Eng. Prog.,90, 39 (1994).
E. S. Behrens, S. Ikeda, T. Yamashita, G. Mittelbach, M. Yanai:Power Engineering, 49 (1991).
J. N. Armor:Appl. Catal. B: Environmental,1, 221 (1992).
W. Held, A. Koenig, T. Richter, L. Puppe: SAE Paper 900496 (1990).
M. Iwamoto, H. Yahiro, S. Shundo, Y. Yuu, N. Mizuno:Appl. Catal.,69, L15 (1991).
H. Hamada, Y. Kintaichi, M. Sasaki, T. Ito:Appl. Catal.,64, L1 (1990).
H. Hamada:Catal. Today,22, 21 (1994).
M. Iwamoto, H. Hamada:Catal. Today,10, 57 (1991).
M. Iwamoto:Zeolites and Related Microporous Materials: State of the Art 1994, (Eds J. Weitkamp, H. G. Karge, H. Pfeifer and W. Hoelderich),Studies in Surface Science and Catalysis, Vol. 84, p. 1395. Elsevier, Amsterdam 1994.
S.-E. Park, G. M. Kim, S. H. Lee, J. S. Chang, J. H. Lee: Korea Pat. Appl. (1995).
Y. Li, J. N. Armor:Appl. Catal. B: Environmental,2, 239 (1993).
W. F. Libby:Science,171, 499 (1971).
S. C. Sorenson, J. A. Wronkiewicz, L. B. Sis, G. P. Wirtz:Bull. Am. Ceram. Soc.,53, 446 (1974).
H. Taguchi, D. Matsuda, M. Nagao, K. Tabata:J. Mater. Sci. Lett.,14, 12 (1995).
Y. Teraoka, H. Fukuda, S. Kagawa:Chem. Lett., 1 (1990).
J.-J. Liang, H.-S. Weng:Ind. Eng. Chem. Res.,32, 2563 (1993).
E. Kikuchi:Shokubai,35, 530 (1993).
M. Sasaki, H. Hamada, Y. Kintaichi, T. Ito:Catal. Lett.,15, 297 (1992).
J. O. Petunchi, G. Sill, W. K. Hall:Appl. Catal. B,2, 303 (1993).
M. Iwamoto, H. Yahiro, N. Mizuno:Proc. 9th Int. Zeolite Conf., Vol.II, 177 (1992).
A. Obuchi, A. Ogata, K. Mizuno, A. Ohi, M. Nakamura, H. Ohuchi:J. Chem. Soc., Chem. Commun., 247 (1992).
T. Inui, S. Kojo, M. Shibata, T. Yoshida, S. Iwamoto:Studies in Surface Science and Catalysis,69, 355 (1991).
S.-E. Park, J. H. Lunsford:Inorg. Chem.,26, 1987 (1993).
J. M. D. Tascon, L. Gonzalez Tejuca, C. H. Rochester:J. Catal.,95, 558 (1985).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Park, SE. Selective catalytic reduction of NO over metal oxides incorporated zeolites. React Kinet Catal Lett 57, 339–348 (1996). https://doi.org/10.1007/BF02064747
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02064747