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Co(salen) catalyzed oxidation of oximes with t-butyl hydroperoxide

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Abstract

Co(salen) catalyzed the oxidation of oximes with t-butyl hydroperoxide to give the parent carbonyl compounds, providing a new convenient route to deoximation reaction. A plausible mechanism involves a substrate radical intermediate.

Abstract

Co(сален) катализирует окисление оксимов с помощью трет-бутилгидропероксида, давая соответствующие карбонильные соединения. Это новый удобный путь реакции деоксимации. Вероятный механизм заключает в себе образование промежуточного радикала из субстрата.

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Author notes

  1. A. Nishinaga

    Present address: Department of Applied Chemistry, Osaka Institute of Technology, Ohmiya 5, Asahi-ku, 535, Osaka, Japan

Authors and Affiliations

  1. Department of Synthetic Chemistry, Kyoto University, Yoshida, Kyoto, Japan

    A. Nishinaga, S. Yamazaki, T. Miwa & T. Matsuura

Authors
  1. A. Nishinaga
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  2. S. Yamazaki
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  3. T. Miwa
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  4. T. Matsuura
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Nishinaga, A., Yamazaki, S., Miwa, T. et al. Co(salen) catalyzed oxidation of oximes with t-butyl hydroperoxide. React Kinet Catal Lett 43, 273–276 (1991). https://doi.org/10.1007/BF02064684

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  • DOI: https://doi.org/10.1007/BF02064684

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