Skip to main content
SpringerLink
Log in

Isokinetic temperature of the Diels-Alder reaction of hexachlorocyclopentadiene with N(o-aryl)-imides of cis-4-cyclohexene-1,2-dicarboxylic acid

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

The existence of an isokinetic relation in the reaction series of N(o-aryl)imides of cis-4-cyclohexene-1,2-dicarboxylic acid (cis-4-CHDA) has been examined to prove the uniformity of the mechanism of their reaction with hexachlorocyclopentadiene (HCP). The mean isokinetic temperature found by correlations from various relations is 558±15 K.

Abstract

Данное сообщение посвящено проверке существования изокинетического соотношениа в реакционной серии (о-арил) имидов цис-4-циклогексен-1, 2-дикарбоновой кислоты (цис-4-ЦГ ДК) для доказательства однородности механизма реакции с гексахлорциклопехтадиеном (ГХЦПД). Среднее значание изокинетической температуры, найденное при помощи корреляционных уравнений из различных зависимостей, оказалось равным 558±15 °К.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. S. Salakhov, N. F. Musaeva, A. A. Aleskerov, S. N. Suleimanov, T. A. Kopylova: Kinet. Katal. (in press).

  2. M. S. Salakhov, M. M. Guseinov: Chem. Tech.,1, 44 (1978).

    Google Scholar 

  3. M. S. Salakhov, N. F. Musaeva, M. M. Guseinov, S. N. Suleimanov: Zh. Org. Khim.,13, 561 (1977).

    Google Scholar 

  4. M. S. Salakhov, N. F. Musaeva, A. A. Aleskerov, S. N. Suleimanov: Organic Reactivity,15, 272 (1978).

    Google Scholar 

  5. L. E. Leffler: J. Org. Chem.,20, 1202 (1955).

    Google Scholar 

  6. L. E. Leffler, E. Grunwald: Rates and Equilibria of Organic Reactions. J. Wiley Sons, New York 1963.

    Google Scholar 

  7. O. Exner: Collect. Czech. Chem. Commun.,29, 1094 (1964).

    Google Scholar 

  8. R. C. Petersen: J. Org. Chem., 29, 2133 (1964).

    Google Scholar 

  9. V. A. Palm: Fundamentals of the Quantitative Theory of Organic Reactions, Khimiya, Leningrad 1977.

    Google Scholar 

  10. O. Exner: Nature,201, 488 (1964).

    Google Scholar 

  11. V. V. Sinev, O. F. Ginzburg, E. I. Kvyat: Zh. Obshch. Khim.,38, 112 (1968).

    Google Scholar 

  12. C. D. Ritchie, W. E. Sager: Progress in Physical Organic Chemistry, Vol. 2. J. Wiley and Sons, New York 1964.

    Google Scholar 

  13. A. Worsing, D. Heffner: Methods of Experimental Data Processing. IL, Moskva 1949.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Instite of Organochlorine Synthesis, Sumgait, USSR

    M. S. Salakhov & N. F. Musaeva

Authors
  1. M. S. Salakhov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. F. Musaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Salakhov, M.S., Musaeva, N.F. Isokinetic temperature of the Diels-Alder reaction of hexachlorocyclopentadiene with N(o-aryl)-imides of cis-4-cyclohexene-1,2-dicarboxylic acid. React Kinet Catal Lett 12, 281–286 (1979). https://doi.org/10.1007/BF02064256

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02064256

Keywords

Search

Navigation