Skip to main content
SpringerLink
Log in

Light olefin production from CO/H2 over silica supported Fe/Mn/K catalysts derived from a bimetallic carbonyl anion, [Fe2Mn(CO)12]−

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

Fe/Mn/K catalysts derived from support of the anionic carbonyl, [Fe2Mn(CO)12]− on silica were compared with catalysts prepared by aqueous impregnation methods, and found to be more selective for production of C2−C4 olefins. Addition of K had little effect, whereas variations in reaction conditions altered selectivity owing to secondary reactions of the alkene products.

Abstract

Катализаторы Fe/Mn/K, получаемые нанесением анионного карбонила, [Fe2Mn(CO)12]−, на окись алюминия, сравнивались с катализаторами, нанесенными методом водного импрегнирования, и оказались более селективными для получения олефинов C2−C4. Добавление К оказывает слабый эффект, в то время как изменение экспериментальных условий изменяет селективность, вследствие вторичных реакций алкеновых продуктов.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. S. Mohammed, B. Schmidt, D. Schneidt, M. Ralek: Chem.-Ing.-Tech.,51, 739 (1979).

    Google Scholar 

  2. B. Bussemier, C. D. Frohning, B. Cornils: Hydrocarbon Process., (11), 105 (1976).

    Google Scholar 

  3. C. H. Young, A. G. Oblad: Amer. Chem. Soc. Div. Petr. Chem., Prepr.23, 513 (1978).

    Google Scholar 

  4. H. Kolbel, K. D. Tillmetz: Ger. Pat. 2,507,647.

  5. Ruhrchemie: Ger. Pat. 2,518,964; Ger. Pat. 2,518,982; U.K. Pat. 1,512,743.

  6. A. L. Dent, M. Lin: Adv. Chem. Ser.,178, 47 (1978).

    Google Scholar 

  7. D. Commereuc, Y. Chauvin, F. Hughes, J. M. Bassett, D. Olivier: J.C.S. Chem. Comm., 154 (1980).

  8. G. B. McVicker, M. A. Vannice: J. Catal.,63, 25 (1980).

    Google Scholar 

  9. J. Bassett, Y. Chauvin, D. Commereuc, A. Smith, A. Theolier: Ger. Pat. 2,822,656.

  10. U. Anders, W. A. G. Graham: J.C.S. Chem. Commun., 291 (1966).

  11. H. Jaeger: unpublished results.

  12. N. Nahon, V. Perrichon, P. Turlier: React. Kinet. Catal. Lett.,12, 139 (1979).

    Google Scholar 

  13. T. Okuhara, K. Kobayashi, T. Kimura, M. Misono, Y. Yoneda: J.C.S. Chem. Commun., 1114 (1981).

  14. H. Schulz, B. R. Rao, M. Elstner: Erdol Kohle,23, 651 (1970).

    Google Scholar 

  15. F. Hughes, B. Gesson, J. A. Dalmor, J. M. Bassett, D. Olivier: Nouv. J. Chim.,5, 207 (1981).

    Google Scholar 

  16. H. Pichler, J. Schulz, F. Hojabri: Brennst. Chem.,45, 215 (1964).

    Google Scholar 

  17. E. L. Kugler: Amer. Chem. Soc. Div. Petr. Chem., Prepr.,25, 564 (1980).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. CSIRO Surface Science and Catalysis Laboratory, Division of Materials Science, University of Melbourne, 3052, Parkville, Vic, Australia

    L. Bruce, G. Hope & T. W. Turney

Authors
  1. L. Bruce
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. Hope
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. W. Turney
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bruce, L., Hope, G. & Turney, T.W. Light olefin production from CO/H2 over silica supported Fe/Mn/K catalysts derived from a bimetallic carbonyl anion, [Fe2Mn(CO)12]− . React Kinet Catal Lett 20, 175–180 (1982). https://doi.org/10.1007/BF02063605

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02063605

Keywords

Search

Navigation