Abstract
Microspherical and uniform Fe–Zr–Ce–K catalysts were prepared by the microwave assisted precipitation followed by impregnation and promoted CO2 hydrogenation toward advantageous synthesis of light olefins. The reducibility, surface basicity and surface atom composition of the catalysts was tuned as the Ce content was varied. The ceria spacer restrained the growth of the Fe2O3 crystallite. Ce addition weakened the interaction between Fe species and zirconia and the reduction of the Fe species became easier. On 35Fe–7Zr–1Ce–K at 320 °C and 2 MPa, the conversion of CO2 and the selectivity of C2–C4 olefins were 57.34 and 55.67%, respectively. The ratio of olefin/paraffin was 7. The selectivity of CO and C5+ hydrocarbons were 3 and 15.87%, respectively. The enhanced performance is attributed to intensified bifunctional activity toward CO hydrogenation as well as the reverse water–gas shift reaction.
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Kondratenko EV, Mul G, Baltrusaitis J, Larrazábal GO, Pérez-Ramírez J (2013) Energy Environ Sci 6:3112–3135
Visconti CG, Martinelli M, Falbo L, Infantes-Molina A, Lietti L, Forzatti P, Iaquaniello G, Palo E, Picutti B, Brignoli F (2017) Appl Catal B 200:530–542
Ma J, Sun N, Zhang X, Zhao N, Xiao F, Wei W, Sun Y (2009) Catal Today 148:221–231
Saeidi S, Amin NAS, Rahimpour MR (2014) J CO2 Util 5:66–81
He M (2017) Sci China Chem 60:1145–1146
Gao P, Li S, Bu X, Dang S, Liu Z, Wang H, Zhong L, Qiu M, Yang C, Cai J, Wei W, Sun Y (2017) Nature Chem. https://doi.org/10.1038/nchem.2794
Phongamwong T, Chantaprasertporn U, Witoon T, Numpilai T, Poo-arporn Y, Limphirat W, Donphai W, Dittanet P, Chareonpanich M, Limtrakul J (2017) Chem Eng J 316:692–703
Zhang J, Lu S, Su X, Fan S, Ma Q, Zhao T (2015) J CO2 Util 12:95–100
Wei J, Ge Q, Yao R, Wen Z, Fang C, Guo L, Xu H, Sun J (2017) Nat Commun. https://doi.org/10.1038/ncomms15174
Weatherbee GD, Bartholomew CH (1984) J Catal 87:352–362
Riedel T, Schaub G, Jun K, Lee K (2001) Ind Eng Chem Res 40:1355–1363
Van Der Laan GP, Beenackers AACM (1999) Catal Rev Sci Eng 41:255–318
Wang W, Wang S, Ma X, Gong J (2011) Chem Soc Rev 40:3703–3723
Lee MD, Lee JF, Chang CS (1989) Bull Chem Soc Jpn 62:2756–2758
You Z, Deng W, Zhang Q, Wang Y (2013) Chin J Catal 34:956–963
Herranz T, Rojas S, Pérez-Alonso FJ, Ojeda M, Terreros P, Fierro JLG (2006) Appl Catal A 311:66–75
Kishan G, Lee MW, Nam SS, Choi MJ, Lee KW (1998) Catal Lett 56:215–219
Wang J, You Z, Zhang Q, Deng W, Wang Y (2013) Catal Today 215:186–193
Al-Dossary M, Ismail AA, Fierro JLG, Bouzid H, Al-Sayari SA (2015) Appl Catal B 165:651–660
Dorner RW, Hardy DR, Williams FW, Willauer HD (2011) Catal Commun 15:88–92
Wambach J, Baiker A, Wokaun A (1999) Phys Chem Chem Phys 1:5071–5080
Su X, Zhang J, Fan S, Ma Q, Zhao T-S (2015) RSC Adv 5:80196–80202
Mohamed MM, Salama TM, Othman AI, El-Shobaky GA (2005) Appl Catal A 279:23–33
Querino PS, Bispo JRC (2005) Rangel MdC. Catal Today 107–108:920–925
Yoshikawa K, Sato H, Kaneeda M, Kondo JN (2014) J CO2 Util 8:34–38
özkara-Aydınoğlu Ş, Ataç Ö, Gül ÖF, Kınayyiğit Ş, Şal S, Baranak M, Boz İ (2012) Chem Eng J 181–182:581–589
Deshmane VG, Adewuyi YG (2012) Micropor Mesopor Mater 148:88–100
Dorner RW, Hardy DR, Williams FW, Willauer HD (2010) Catal Commun 11:816–819
Hu Y, Jin H, Liu J, Hao D (2000) Chem Eng J 78:147–152
Baneshi J, Haghighi M, Jodeiri N, Abdollahifar M, Ajamein H (2014) Energy Convers Manage 87:928–937
Jozwiak WK, Kaczmare KE, Maniecki TP, Ignaczak W, Maniukiewicz W (2007) Appl Catal A 326:17–27
Ning W, Koizumi N, Chang H, Mochizuki T, Itoh T, Yamada M (2006) Appl Catal A 312:35–44
Gao X, Shen J, Hsia Y, Chen Y (1993) J Chem Soc Faraday Trans 89:1079–1084
Choi PH, Jun KW, Lee SJ, Choi MJ, Lee KW (1996) Catal Lett 40:115–118
van den Berg FR (2003) CrajéMWJ, van der Kraan AM, Geus JW. Appl Catal A 242:403–416
Hakeem AA, Vásquez RS, Rajendran J, Li M, Berger RJ, Delgado JJ, Kapteijn F, Makkee M (2014) J Catal 313:34–45
Cai W, de la Piscina PR, Toyir J, Homs N (2015) Catal Today 242:193–199
Dry ME, Shingles T, Boshoff LJ, Oosthuizen GJ (1969) J Catal 15:190–199
Riedel T, Schulz H, Schaub G, Jun KW, Hwang JS, Lee KW (2003) Top Catal 26:41–54
Ordomsky VV, Legras B, Cheng K, Paul S, Khodakovet AY (2015) Catal Sci Technol 5:1433–1437
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Financial support from Natural Science Foundation of China (21666030, 21366025), the National First-rate Discipline Construction Project of Ningxia (Chemical Engineering & Technology, NXYLXK2017A04) and Special Prophase Project of Basic Research Program of China (2012CB723106) are appreciated.
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Zhang, J., Su, X., Wang, X. et al. Promotion effects of Ce added Fe–Zr–K on CO2 hydrogenation to light olefins. Reac Kinet Mech Cat 124, 575–585 (2018). https://doi.org/10.1007/s11144-018-1377-1
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DOI: https://doi.org/10.1007/s11144-018-1377-1