Skip to main content
Log in

Donor-acceptor concept of covalent interaction of substrate with catalysts

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

In terms of a unitary approach, the ability of complexes, clusters and metals of transition and nontransition elements for covalent interaction with reagents has been analyzed. the requirements for the catalysts to be efficient in the covalent activation of substrates have been formulated.

Abstract

В рамках единого подхода проанализирована способность к ковалентному взаиьодействию с реагентами комплексов, кластеров и металлов переходныхи неперешодных элементов. Сформулированы требования к эффективным катализаторам ковалентной активации субстратов.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. D. A. Dowden, D. Wells: Actes 2-me Congrés Intern. de Catalyse, Paris 1960, vol 2, 1489. Technip., 1961.

    Google Scholar 

  2. D. A. Dowden, P. W. Reynolds: Disc. Faraday Soc.,8, 184 (1950).

    Google Scholar 

  3. F. D. Mango: Adv. Catal.,20, 291 (1969).

    Google Scholar 

  4. R. D. Levy, M. Boudart: Science,181, 547 (1973).

    Google Scholar 

  5. Y. S. Dewar, R. C. Dougherty: The PMO Theory of Organic Chemistry. Plenum Press, New York 1975.

    Google Scholar 

  6. I. B. Bersuker: Kinet. Katal.,18, 1261 (1977).

    Google Scholar 

  7. R. Ugo: Proc. 5th Intern. Congress Catal., p. 19. American Elsevier Co., New York 1973.

    Google Scholar 

  8. G. K. Boreskov: Theoretical Problems of Catalysis, p. 5. Novosibirsk 1977.

  9. M. B. Kuzminskii, A. A. Bagatur'yants, G. M. Zhidomirov, V. B. Kazanskii: Kinet. Katal.,22, 151 (1981).

    Google Scholar 

  10. Y. Andzeim: Surf. Sci.,108, 561 (1981).

    Google Scholar 

  11. L. V. Gurvich, G. V. Karachevtsev, V. N. Kondratiev, Yu. A. Lebedev, V. A. Medvedev, V. K. Potapov, Yu. S. Khodeev: Dissociation Energy of Chemical Bonds. Ionization Potentials and Affinity to Electron. Nauka, Moskva 1975.

    Google Scholar 

  12. V. V. Nemoshkalenko, V. G. Aleshin: Electron Spectroscopy. Naukova Dumka, Kiev 1976.

    Google Scholar 

  13. V. S. Fomenko, I. A. Podchernyaeva: Emission and Absorption Properties of Substances and Materials. Atomizdat, Moskva 1975.

    Google Scholar 

  14. L. E. Orgel: An Introduction to Transition Metal Chemistry. John Wiley & Sons Inc., New York 1961.

    Google Scholar 

  15. O. V. Krylov, V. F. Kiselev: Adsorption and Catalysis on Transition Metals and their Oxides. Khimiya, Moskva 1981.

    Google Scholar 

  16. R. L. Burwell: in Catalysis. Progress in Research, p. 51. Plenum Press, New York 1973.

    Google Scholar 

  17. A. S. Berenblum, A. G. Knizhnik, S. L. Mund, I. I. Moiseev: Izv. Akad. Nauk SSSR, Ser. Khim.,12, 2711 (1978).

    Google Scholar 

  18. R. C. Baetzold: Adv. Catal.,25, 1 (1976).

    Google Scholar 

  19. V. A. Semikolenov, V. A. Likholobov, Yu. I. Yermakov: Supported Metal Catalysts for Hydrocarbon Conversions, p. 280. Novosibirsk 1978.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sokolovskii, V.D. Donor-acceptor concept of covalent interaction of substrate with catalysts. React Kinet Catal Lett 20, 79–86 (1982). https://doi.org/10.1007/BF02063589

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02063589

Keywords

Navigation