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Stoichiometric number molecularity and multiplicity

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Abstract

On the basis of the polynomial to which the system of pseudo-steady-state equations corresponding to the nonlinear single-route mechanism is reduced (kinetic polynomial), the known concepts of “stoichiometric number” and “molecularity” have been studied. A set of the minimal-integer stoichiometric coefficients is shown to correspond to the kinetic characteristics in the neighborhood of equilibrium.

Abstract

На основе полинома, к которому сводится система уравнений квазистационарности, соответствующая нелинейному одномаршрутному механизму (кинетического полинома) проводится исследование известных понятий —стехиометрического числа и молекулярности. Показано, что набор минимально-целочисленных стехиометрических коэффициентов соответствует кинетическим характеристикам вблизи равновесия.

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Authors and Affiliations

  1. Institute of Catalysis, Novosibirsk, USSR

    G. S. Yablonskii, M. Z. Lazman & V. I. Bykov

Authors
  1. G. S. Yablonskii
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  2. M. Z. Lazman
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  3. V. I. Bykov
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Yablonskii, G.S., Lazman, M.Z. & Bykov, V.I. Stoichiometric number molecularity and multiplicity. React Kinet Catal Lett 20, 73–77 (1982). https://doi.org/10.1007/BF02063588

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  • DOI: https://doi.org/10.1007/BF02063588

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