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ESR studies of slow relaxations of the rate of sulfur dioxide oxidation on vanadium catalyst

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Abstract

Slow changes in the rate of the title reaction are shown to be due to pahse transformations of the active component, in particular, the agglomeration or crystallization of vanadyl complexes. The possible mechanism of these phenomena is discussed.

Abstract

Показано, что медленные изменения скорости реакции обусловлены фазовыми превращениями активного компонента, в частности, агломерацией или кристаллизацией комплексов ванадила. В работе также обсуждается возможный механизи этих явлений.

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Authors and Affiliations

  1. Institute of Catalysis, Novosibirsk, USSR

    S. V. Kozyrev, B. S. Balzhinimaev, G. K. Boreskov, A. A. Ivanov & V. M. Mastikhin

Authors
  1. S. V. Kozyrev
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  2. B. S. Balzhinimaev
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  3. G. K. Boreskov
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  4. A. A. Ivanov
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  5. V. M. Mastikhin
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Kozyrev, S.V., Balzhinimaev, B.S., Boreskov, G.K. et al. ESR studies of slow relaxations of the rate of sulfur dioxide oxidation on vanadium catalyst. React Kinet Catal Lett 20, 53–57 (1982). https://doi.org/10.1007/BF02063584

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  • DOI: https://doi.org/10.1007/BF02063584

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