Abstract
The ammoxidation of pyridinemethanols over V-Mo oxide gave cyanopyridines and the selectivity towards the formation of respective aldehydes changes with the isomeric carbinols. A reaction mechanism is suggested for the formation of nitriles.
Abstract
При окислительном аммонолизе пиридинметанолов на окисях V-Mo образуются цианопиридины. Селективность к образованию соответствующих альдегидов изменяется в ряду изоемрных карбинолов. Предложен механизм реакции образования нитрилов.
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Prasad, A.R., Subrahmanyam, M. Ammoxidation of pyridinecarbinols on V-Mo oxide catalyst. React Kinet Catal Lett 47, 143–146 (1992). https://doi.org/10.1007/BF02063572
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DOI: https://doi.org/10.1007/BF02063572