Skip to main content
SpringerLink
Log in

Thermal activation of complexation reaction on aerosil surface

  • Poster Presentations
  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

The influence of temperature in the 20–100°C range on processes of bimolecular interaction in the aerosil-phenanthrene-trinitrobenzene system has been studied. Temperature-stimulated CTC accumulation on the surface is found. Activation energies of complex formation are estimated. Quenching of phenanthrene fluorescence by acceptor has a mixed static and dynamic character.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. D. Avnir, M. Ottolenghi: Photochemistry in Organized and Constrained Media, ed. V. Ramamurthy. Chapter 12, pp. 535–562. VCH, New York 1991.

    Google Scholar 

  2. A.M. Eremenko, V.P. Kondilenko, V.Ya. Chorny, A.A. Chuiko: Zh. Fiz. Khim.,66, 1566 (1992).

    Google Scholar 

  3. O.I. Yakimova, A.M. Eremenko, A.A. Chuiko: J. Mol. Struct.,218, 447 (1990).

    Google Scholar 

  4. J. Samuel, M. Ottolenghi, D. Avnir: J. Phys. Chem., 1992, in press.

  5. P. De Mayo, L.V. Natarajan, W.R. Ware: Materials of Symposium 18th Meeting American Chemical Society, Washington, D.C. pp 1–19.

  6. V.J. Czekalla, G. Briegleb, W. Herre: Z. Elektrochem.,63, 712 (1959).

    Google Scholar 

  7. C. Reid: J. Chem. Phys.,20, 1212 (1952).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Surface Chemistry, Ukrainian Academy of Sciences, Kiev, Ukraine

    V. P. Kondilenko, V. Ya. Chorny & A. M. Eremenko

Authors
  1. V. P. Kondilenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. Ya. Chorny
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. M. Eremenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kondilenko, V.P., Chorny, V.Y. & Eremenko, A.M. Thermal activation of complexation reaction on aerosil surface. React Kinet Catal Lett 50, 203–207 (1993). https://doi.org/10.1007/BF02062212

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02062212

Keywords

Search

Navigation