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Formation of the active component of a vanadium-molybdenum oxide catalyst in acrolein oxidation

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Abstract

An acrolein-containing reaction mixture reduces V5+ to V4+, accompanied by decomposition of the ammonium salt of vanadium-molybdenum-silicon heteropolyacid (HPA) to form a compound with the tentative composition of VMo3O11+x, which is the active component of the catalyst.

Abstract

Под воздействием акролеисодержащей реакционнюй смеси в катализаторе происходит восстановление V5+ до V4+, сопровождающееся разложением аммонийной соли ванадиймолибденкремниевой ГПК с образованием соединения примерного состава VMo3OII+X, являющегося активным компонентом катализатора для реакуии.

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Authors and Affiliations

  1. Institute of Catalysis, Novosibirsk, USSR

    T. G. Kuznetsova, G. K. Boreskov, T. V. Andrushkevich, L. M. Plyasova, N. G. Maksimov & I. P. Olenkova

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  1. T. G. Kuznetsova
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  2. G. K. Boreskov
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  3. T. V. Andrushkevich
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  4. L. M. Plyasova
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  5. N. G. Maksimov
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  6. I. P. Olenkova
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Kuznetsova, T.G., Boreskov, G.K., Andrushkevich, T.V. et al. Formation of the active component of a vanadium-molybdenum oxide catalyst in acrolein oxidation. React Kinet Catal Lett 12, 531–536 (1979). https://doi.org/10.1007/BF02061767

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  • DOI: https://doi.org/10.1007/BF02061767

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