Abstract
The homogeneous pyrolysis of formaldehyde has been studied under laser heating. At temperatures of 950–1000 K H2CO decomposition is shown to be a radical chain reaction. Methanol formation in formaldehyde pyrolysis is a homogeneous reaction.
Abstract
Проведен гомогенный пиролиз формальдегида методом лазерного нагрева. Показано, что распад H2CO в этих условиях при температуре 950–1000° К является радикальной цепной реакцией. Образование метилового спирта при пиролизе формальдегида является гомогенной реакцией.
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Samsonov, Y.N., Petrov, A.K. & Baklanov, A.V. Homogeneous decomposition of formaldehyde induced by a carbon dioxide laser. React Kinet Catal Lett 5, 435–437 (1976). https://doi.org/10.1007/BF02060891
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DOI: https://doi.org/10.1007/BF02060891