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Possible radiochemical separations of anionic radionuclides by amorphous hydrous titanium dioxide

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Abstract

Ion-exchange selectivities towards oxoanions and halide ions were studied for radio-chemical applications by an amorphous hydrous titanium dioxide (Am-HTDO) as functions of pH and concentration. The selectivity series was found to be Mo(VI)<W(VI)<P(V)<As(V)<Sb(V) for micro-amounts at pH 9 and Br−≈Cl−≪F− for macro-amounts. A feasibility was suggested for radiochemical separations of32P by35Cl(n,α)32P and77Br by75As(α, 2n)77Br, and selective removal of anionic radionuclides.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Tokyo Institute of Technology, 2-12-1, Ookayama, Meguro-ku, 152, Tokyo, Japan

    M. Tsuji & M. Abe

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  1. M. Tsuji
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  2. M. Abe
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Synthetic Inorganic Ion-Exchange Materials. XLIII.

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Tsuji, M., Abe, M. Possible radiochemical separations of anionic radionuclides by amorphous hydrous titanium dioxide. Journal of Radioanalytical and Nuclear Chemistry, Articles 102, 283–294 (1986). https://doi.org/10.1007/BF02047904

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  • DOI: https://doi.org/10.1007/BF02047904

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