Skip to main content
Log in

Radiochemical solvent extraction of Au(III) using thionalide in ethyl methyl ketone/iso buthyl methyl ketone

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

A radiochemical method for the determination of gold using198Au, has been developed. It is based on the synergistic extraction of Au(III) with thionalide (TA) in ethyl methyl ketone (EMK) or isobuthyl methyl ketone (IBMK) at pH 5.0.Effect of various parameters such as pH, nature of solvent and interferences due to other radionuclides have been studied. The method can be used up to 25 ng of Au.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. N. R. DAS, P. S. CHAKRABORTY, S. N. BHATTACHARYYA, J. Radioanal. Chem., 36 (1977) 419.

    Google Scholar 

  2. R. V. PARISH, S. M. COTRILL, Gold Bull., 20 (1987) 3.

    Google Scholar 

  3. K. LANDE, Munch. Med. Wochenschr., 74 (1927) 1123; J. FORESTIER, Bull. Mem. Soc. Med. Hop. Paris, (1929) 323; T. N. FRASER, Ann. Rheum. Dis., 4 (1945) 71.

    Google Scholar 

  4. R. T. PEREZ, P. C. SANCHEZ, C. M. HARMANDEZ, C. L. MARTINEZ, Microchim Acta, 1 (1983) 395.

    Google Scholar 

  5. K. S. PATEL, K. H. LIESER, Anal. Chem., 58 (1986) 1547.

    Article  Google Scholar 

  6. M. YILONG, L. PEIBIABO, Z. ZAOFAN, Huaxue Tanghao, 7 (1984) 17.

    Google Scholar 

  7. W. SHU, Z. SHUYAN, P. TIANGANG, L. YUE, Lanzhou, Daxue, Xuebao, Zivan Kexueban, 19 (1983) 131.

    Google Scholar 

  8. K. R. RAKHIMOV, P. K. NISHANOV, O. U. KARIMKULOV, M. ERMAZAROV, A. G. GANIER, Radioakt. Metody. Anal. Óbektov. Prir. Proishozhd, (1980) 8.

  9. A. N. SHILO, M. S. SAKHAROVA, S. K. RYAKHOVSKAYA, Dokl. Acad. Nauk. SSSR, 255. (1980) 195.

    Google Scholar 

  10. H. ZHI-TEI, T. LIANG-CHENG, K. O. HSEUCH, TUNG PAO, 20 (1975) 216.

  11. J. C. LAUL, D. R. CASE, M. WECHTER, F. SCHMITT, M. E. LIPSCHUTZ, J. Radioanal. Chem., 4 (1970) 241.

    Google Scholar 

  12. G. BING, K. YANG, Jilian Dauxe Kexue Xuebao, 1 (1984) 117.

    Google Scholar 

  13. T. S. LO, L. CHOU, C. C. TU, H. L. LIU MING, Fen. Hsi Hua Hsuch, 8 (1980) 77.

    Google Scholar 

  14. F. O. SIMON, H. T. MULLARD, Anal. Chem., 40 (1968) 1150.

    Article  Google Scholar 

  15. C. GUANGZHOU, Z. ZHAO, Gaodeng Xuexiao Huaxue Xuebao, 6 (1985) 211.

    Google Scholar 

  16. T. R. SYKES, L. G. S. NEWSHAM, M. J. APPS, A. A. NAUJAIM, J. Radioanal. Chem., 69 (1982) 441.

    Google Scholar 

  17. P. S. TJIOE, K. J. VOLKERS, J. J. KROON, J. J. M. DE GOEIJ, S. K. THE; Int. J. Environ. Anal. Chem., 17 (1984) 13.

    PubMed  Google Scholar 

  18. V. I. PARAMANOVA, S. A. BARTENEV, A. M. KLEMINA, E. L. ZHUGAVLEVA, V. E. ZHUCHKO, Geokhimiya, 6 (1987) 890.

    Google Scholar 

  19. E. TASKEV, M. KARAIVANOVA, T. GRIGOROV, J. Radioanal. Nucl. Chem. Articles, 120 (1988) 75.

    Article  Google Scholar 

  20. P. SEHUTYSER, A. GOVAERTS, R. DAMS, J. HOSTE, J. Radioanal. Chem., 37 (1977) 651.

    Google Scholar 

  21. R. K. IYER, K. R. KRISHNAMOORTHY, J. Radioanal. Chem., 33 (1976) 243.

    Google Scholar 

  22. S. J. PARRY, Analyst, 105 (1980) 1157.

    Article  Google Scholar 

  23. M. R. LOUIS, Geostand, Newsl., 11, (1987) 151.

    Google Scholar 

  24. D. E. GILLUM, W. D. EHMANN, Radiochim. Acta, 16 (1971) 123.

    Google Scholar 

  25. L. CHEN, Y. SHA, He Huaxue Yu Fangshe Huaxue, 7 (1985) 63.

    Google Scholar 

  26. R. A. NADKARNI, B. C. HALDAR, Radiochem. Radioanal. Lett., 11 (1972) 367.

    Google Scholar 

  27. D. L. SAMUDRALWAR, A. N. GARG, Unpublished results.

  28. W. ZMIJEWSKA, Radiochem. Radioanal. Lett., 21 (1975) 91.

    Google Scholar 

  29. W. ZMIJEWSKA, H. POLKOWSKA MONTRENKO, H. STOKOWSKA, J. Radioanal. Nucl. Chem. Articles, 116 (1987) 243.

    Article  Google Scholar 

  30. R. N. MISHRA, S. S. GUHA SIRCAR, J. Indian Chem. Soc., 32 (1955) 127.

    Google Scholar 

  31. K. TERADA, K. MATSUMOTO, Y. TANUGUKU, Anal. Chim. Acta, 147 (1983) 411.

    Article  Google Scholar 

  32. V. M. TARAYAN, G. N. SHAPOSHNIKOVA, Dokl. Akad. Nauk. Arm. SSSR, 45 (1987) 21.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Weginwar, R.G., Lanjewar, R.B. & Garg, A.N. Radiochemical solvent extraction of Au(III) using thionalide in ethyl methyl ketone/iso buthyl methyl ketone. Journal of Radioanalytical and Nuclear Chemistry, Articles 134, 173–180 (1989). https://doi.org/10.1007/BF02047280

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02047280

Keywords

Navigation