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Geminate cations and anions in halocarbon systems: Life time, solvent effects and details of early stages

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Abstract

Studies on the ionization processes in halocarbon systems, particularily with CCl4, have led to controversial interpretations in the past. Some of the reasons for discrepancies in CCl4-systems are known today. In a general way, they are typical for most halocarbons, though possibly not always equally dominant. The following aspects are discussed in the paper: complex formation, solvent and caging effects, geminate ion fragmentation, cross geminate charge transfer and delayed geminate ion neutralization through ion pair formation.

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  1. Swiss Federal Institute of Technology, Laboratory for Physical Chemistry, ETH-Zentrum, 8092, Zürich, (Switzerland)

    R. E. Bühler

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  1. R. E. Bühler
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Bühler, R.E. Geminate cations and anions in halocarbon systems: Life time, solvent effects and details of early stages. Journal of Radioanalytical and Nuclear Chemistry, Articles 101, 329–338 (1986). https://doi.org/10.1007/BF02042434

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  • DOI: https://doi.org/10.1007/BF02042434

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