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Assessment of an ultrafiltration technique for the fractionation of radionuclides associated with humic material

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Abstract

Experiments have been carried out with well characterised laboratory solutions to establish the physico-chemical behaviour of a suite of radionuclides in the presence of humic and fulvic acids using single flat membrane ultrafilters. Because of the uncertainties associated with the methodology, an approach has been adopted using mass balance determinations to assess the performance of the ultrafiltration process and facilitate the interpretation of the fractionation data. The size distribution of radionuclide-ligand complexes are reported and the results are discussed in the context of interpreting environmental data with more confidence.

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References

  1. M. B. LOVETT, D. M. NELSON, in: Techniques for Identifying Transuranic Speciation in Aquatic Environments, Panel Proc. Ser., Ispra, IAEA Vienna, 1981. p. 27.

    Google Scholar 

  2. D. M. NELSON, M. B. LOVETT, Nature 276 (1978) 599.

    PubMed  Google Scholar 

  3. R. J. PENTREATH, B. R. HARVEY, M. B. LOVETT, in: Speciation of Fission and Activation Products in the Environment, R. A. BULMAN, J. R. COOPER (Eds), Elsevier, London and New York, 1986, p. 312.

    Google Scholar 

  4. J. HAMILTON-TAYLOR, M. KELLY, S. MUDGE, K. BRADSHAW, J. Environ. Radioact, 5 (1987) 409.

    Google Scholar 

  5. D. M. NELSON, K. A. ORLANDINI, W. R. PENROSE, J. Environ. Radoact., 9 (1989) 189.

    Google Scholar 

  6. D. M. NELSON, W. R. PENROSE, J. O. KARTTUNEN, P. MEHLHAFF, Environ. Sci. Technol., 19 (1985) 127.

    Google Scholar 

  7. S. MUDGE, J. HAMILTON-TAYLOR, M. KELLY, K. BRADSHAW, J. Environ. Radioact., 8 (1988) 217.

    Google Scholar 

  8. F. R. LIVENS, J. Environ. Radiact., 70 (1991) 183.

    Google Scholar 

  9. S. D. DE MORA, R. M. HARRISON, Water Res., 17 (1983) 723.

    Google Scholar 

  10. N. OGURA, Marine Biology, 24 (1974) 305.

    Google Scholar 

  11. J. J. ALBERTS, J. E. SCHINDLER, D. E. NUTTER, J. E. DAVIS, Geochim. Cosmochim. Acta, 40 (1976) 369.

    Google Scholar 

  12. J. R. WHEELER, Limnol. Oceanogr., 21 (1976) 846.

    Google Scholar 

  13. J. C. T. KWAK, R. W. P. NELSON, D. S. GAMBLE, Geochim., Cosmochim. Acta, 41 (1977) 993.

    Google Scholar 

  14. J. BUFFLE, P. DELADOEY, W. HAERDI, Anal. Chim. Acta, 101 (1978) 339.

    Google Scholar 

  15. C. STAUB, J. BUFFLE, W. HAERDI, Anal. Chem., 56 (1984) 2843.

    Google Scholar 

  16. B. SALBU, H. E. BJORNSTAD, N. S. LINDSTROM, E. LYDERSEN, E. M. BREVIK, J. P. RAMBAEK, P. E. PAUS, Tantala, 32 (1985) 907.

    Google Scholar 

  17. B. G. WHITEHOUSE, Limnol. Oceanorg., 35 (1990) 1368.

    Google Scholar 

  18. Y. TANIZAKI, T. SHIMOKAWA, M. NAKAMURA, Environ. Sci. Technol, 26 (1992) 1433.

    Google Scholar 

  19. L. E. SOJO, Anal. Chim. Acta, 258 (1992) 219.

    Google Scholar 

  20. F. J. STEPHENSON, in: Humus Chemistry, Wiley, New York, 1982, Ch. 2.

    Google Scholar 

  21. M. B. LOVETT, S. J. BOGGIS, P. BLOWERS, Aquat. Environ. Prot.: Analyt, Meth., MAFF Direct. Fish Res., Lowestoft, No. 7 (1990), 36 p.

  22. C. W. BAKER, A. K. YOUNG, Internal Rep., MAFF Direct. Fish. Res., Lowestoft, No. 17 (1989), 31 p.

  23. D. J. CARLSON, M. L. BRANN, T. H. MAGUE, L. H. MAYER, Mar. Chem., 16 (1985) 155.

    Google Scholar 

  24. J. HILTON, W. DAVISON, F. LIVENS, M. KELLY, J. HAMILTON-TAYLOR, DOE Rep. PECD 7/9 (1988) 385.

  25. K. S. LEONARD, B. R. HARVEY, R. J. FENN, CEC Final Rep. Contract No. B1602046. UK(H), 1989, 40 p.

  26. H. IRVING, R. J. P. WILLIAMS, J. Chem. Soc., (1953) 3192.

  27. K. GOSH, M. SCHNITZER, Soil. Sci., 129 (1980) 266.

    Google Scholar 

  28. N. A. MARLEY, J. S. GAFFNEY, K. A. ORLANDINI, K. C. PICEL, G. R. CHOPPIN, Sci., Total Environ, 113 (1992) 159.

    Google Scholar 

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Leonard, K.S., Harvey, B.R., Woodhead, R.J. et al. Assessment of an ultrafiltration technique for the fractionation of radionuclides associated with humic material. Journal of Radioanalytical and Nuclear Chemistry, Articles 181, 309–320 (1994). https://doi.org/10.1007/BF02037637

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  • DOI: https://doi.org/10.1007/BF02037637

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