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PIGE and PIXE analyses of pentasil type boroaluminosilicates

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Abstract

The elemental composition of various synthetic crystalline sodium-boroaluminosilicates, especially the Al content and the silicon to aluminium bulk ratio, were determined by means of the combination of PIGE (Proton-Induced Gamma-Ray Emission Spectrometry) and PIXE (Proton-Induced X-Ray Emission Spectrometry). Light elements (B, O, Na, Al) were determined by means of gamma-ray emission. Proton-induced X-ray emission provided information on heavy elements present down to impurities. The Si/Al ratios, which mainly determine the catalytic and adsorptive properties of the zeolites, are compared with those obtained with other methods (EPMA, H2O sorption capacity) and show good agreement.

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Author notes

  1. H. U. Frey

    Present address: Technikum Mikroelektronik, VEB Mikroelektronik “Karl Marx”, Rudolfstr. 47, DDR-5010, Erfurt, GDR

Authors and Affiliations

  1. Sektion Physik, WB Angewandte Kernphysik, Karl-Marx-Universität, Linnestrasse 5, DDR-7010, Leipzig, (GDR)

    H. U. Frey & G. Otto

  2. Sektion Chemie, WB Heterogene Katalyse, Technische Hochschule “Carl Schorlemmer” Leuna-Merseburg, Otto-Nuschke-Strasse, DDR-4200, Merseburg, (GDR)

    W. Reschetilowski, B. Unger & K. -P. Wendlandt

Authors
  1. H. U. Frey
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  2. G. Otto
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  3. W. Reschetilowski
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  4. B. Unger
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  5. K. -P. Wendlandt
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Frey, H.U., Otto, G., Reschetilowski, W. et al. PIGE and PIXE analyses of pentasil type boroaluminosilicates. Journal of Radioanalytical and Nuclear Chemistry, Articles 120, 281–287 (1988). https://doi.org/10.1007/BF02037343

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  • DOI: https://doi.org/10.1007/BF02037343

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