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Synergistic extraction of cobalt(II) with oxine/decanoic acid solution mixtures in benzene and chloroform

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Abstract

Synergistic extraction of Co(II) with 8-hydroxyquinoline (Hq)/decanoic acid [(HR)2] solution mixtures in benzene and chloroform was carried out at 25°C. The aqueous ionic strength and the total concentration of cobalt(II) were 0.1 (NaCl) and 1·10−5–1·10−3M, respectively. The synergistic effect is interpreted by the formation of the mixed ligand ion-pair complexes: [(Coq(Hq)2(HR))+, R−] and [(Coq(Hq)2(HR)3)+, R−] in benzene and chloroform, respectively.

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Authors and Affiliations

  1. Nuclear Chemistry and Radiation Protection Departments, Hot Laboratories and Nuclear Research Centres, Atomic Energy Authority, P.O. Box 13759, Cairo, (Egypt)

    Sh. G. Beheir, M. Aziz & K. Shakir

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  1. Sh. G. Beheir
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  2. M. Aziz
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  3. K. Shakir
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Beheir, S.G., Aziz, M. & Shakir, K. Synergistic extraction of cobalt(II) with oxine/decanoic acid solution mixtures in benzene and chloroform. Journal of Radioanalytical and Nuclear Chemistry, Articles 207, 117–127 (1996). https://doi.org/10.1007/BF02036531

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  • DOI: https://doi.org/10.1007/BF02036531

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